Chemical Analysis Flashcards

(29 cards)

1
Q

What is a pure substance in chemistry?

A

A single element or compound that has not been mixed with any other substance

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2
Q

How can we distinguish pure substances from mixtures?

A

Pure elements and compounds melt and boil at specific temperatures. The melting and boiling point data can be used to distinguish

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3
Q

What is a pure substance in everyday language?

A

A substance that has had nothing added to it, so it is unadulterated and in its natural state e.g. pure milk

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4
Q

What is a formulation?

A

A mixture that has been designed as a useful product, They are often complex mixtures where each chemical has a particular purpose

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5
Q

How are formulations made?

A

By mixing the components in carefully measured quantities to ensure that the product has the required properties.

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6
Q

Give examples of formulations

A

Fuels, cleaning agents, paints, medicines, alloys, fertilisers and foods

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7
Q

What is chromatography used for?

A

To separate mixtures and to give info to help identify substances

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8
Q

What are the two phases involved in chromatography?

A

The mobile phase and the stationary phase

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9
Q

What does the separation of substances in chromatography depend on?

A

The distribution between the stationary and mobile phases

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10
Q

What is expressed as an Rf value?

A

The ratio of the distance moved by a compound (centre of the spot to origin) to the distance moved by the solvent

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11
Q

Give the formula for the Rf value

A
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12
Q

What from chromatography can be used to identify the compounds in a mixture?

A

Different compounds have different Rf values in different solvents.

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13
Q

How can chromatographic methods can be used to distinguish pure substances from impure substances?

A

Compounds in mixture may separate into different spots depending on the solvent, but pure compounds will produce a single spot in all solvents.

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14
Q

What is the test for hydrogen?

A

Use a burning splint held at the open end of a test tube of the gas. Hydrogen will burn rapidly with a pop sound

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15
Q

What is the test for oxygen?

A

Use a glowing splint inserted into a test tube of the gas. The splint will relight if oxygen is present

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16
Q

What is the test for carbon dioxide?

A

Use an aqueous solution of calcium hydroxide (lime water). When it is shaken with or bubbled through limewater, it will turn milky (cloudy)

17
Q

What is the test for chlorine?

A

Damp litmus paper is bleached and turns white when inserted into chlorine gas

18
Q

What are flame tests used for?

A

Used to identify some metal ions. Lithium, sodium, potassium, calcium, and copper compounds all produce distinctive colours in flame tests

19
Q

What are the colours from flame tests for each cation?

A

lithium compounds result in a crimson flame
sodium compounds result in a yellow flame
potassium compounds result in a lilac flame
calcium compounds result in an orange-red flame
copper compounds result in a green flame.

20
Q

What happens if a flame test is used on a mixture of ions?

A

Some flame colours can be masked

21
Q

What is sodium hydroxide used for?

A

Can be used to identify some metal ions

22
Q

What do solutions of aluminium, calcium and magnesium ions form in NaOH?

A

They form white precipitates with NaOH solution. Only aluminium hydroxide precipitate dissolves in excess NaOH

23
Q

What do solutions of copper II, iron II and iron III ions form in NaOH?

A

They form coloured precipitates
Copper II forms a blue precipitate
Iron II forms a green precipitate
Iron III forms a brown precipitate

24
Q

What do carbonates react with dilute acids to form?

A

A salt, water and carbon dioxide gas. The carbon dioxide can be identified with limewater

25
Halide ions in a solution can be identified using what test? What are the different colours of the precipitates?
Added to silver nitrate solution in the presence of dilute nitric acid they form a precipitate. Silver chloride is white Silver bromide is cream Silver iodide is yellow
26
What is the test for sulfate ions in a solution?
They produce a white precipitate with barium chloride solution in the presence of dilute hydrochloric acid
27
Why use instrumental methods to detect and identify elements / compounds?
They are accurate, sensitive and rapid
28
What is FES?
Flame Emission Spectroscopy - an instrumental method used to analyse metal ions in solutions
29
How does FES work?
A sample is put into a flame and the light given out is passed through a spectroscope. The output is a line spectrum that can be analysed to identify the metal ions in the solution and measure their concentrations