Things from the spec i didn't know Flashcards

(38 cards)

1
Q

How did Niels Bohr adapt the nuclear model?

A

Suggested that electrons orbit the nucleus at specific distance (energy levels)

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2
Q

How was Bohr’s theory accepted?

A

His theoretical calculations agreed with experimental observations

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3
Q

How big is the radius of an atom?

A

(1 x 10 ^ -10 m)

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4
Q

What is the relative atomic mass of an element?

A

Average value of atomic mass that takes into account the abundance of all the isotopes of an element

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5
Q

Why is it called the periodic table?

A

Similar properties occur at regular intervals

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6
Q

What did knowledge of isotopes allow scientists to explain about the periodic table?

A

Knowledge of isotopes made it possible to explain why the order based on atomic weights was not always correct.

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7
Q

Describe the alkali metals’ reactions with oxygen

A

Form metal oxides, reactivity increases down the group with faster more vigorous reactions

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8
Q

Describe the alkali metals’ reactions with chlorine

A

Form metal chlorides, all of which are white solids that dissolve in water to make a colourless solution

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9
Q

What do the alkali metals react with water to produce?

A

Metal hydroxides and hydrogen gas

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10
Q

What is observed when lithium reacts with water?

A

Floats and moves slowly on surface of water
Bubbles of hydrogen form
Metal slowly dissolves

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11
Q

What is observed when sodium reacts with water?

A

Melts into shiny, silvery ball due to heat released
Moves quickly across water surface
Bubbles vigorously, fizzes

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12
Q

What is observed when potassium reacts with water?

A

Ignites with lilac flame as hydrogen catches fire
Moves rapidly, crackles
Heat generated can cause explosion of metal

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13
Q

Describe the compounds made when a halogen reacts with a metal

A

Ionic halide
For white or colourless crystal solids
High melting and boiling points
Soluble in water (form electrolytes)

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14
Q

Describe the compounds made when a halogen reacts with a non-metal

A

Covalent halides
Typically gases, liquids or low melting solids
Poor electrical conductors in any state
Distinctive colours or odours

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15
Q

Why do the halogens have increasing melting and boiling points down the group?

A

Atoms get bigger, so stronger intermolecular bonds occur, so more energy required to break them apart

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16
Q

Physical properties of transition metals

A

(compared with G1)
High melting points, densities, hard and strong

17
Q

Chemical properties of transition metals

A

(compared with G1)
React slowly with oxygen, generally unreactive with water, form a wide range of stable halides

18
Q

What are transition metals useful as + other typical properties?

A

Used as catalysts, form coloured compounds, have ions with different charges

19
Q

Describe the FoA in ionic bonding

A

Strong electrostatic forces of attraction between oppositely charged ions

20
Q

Describe the FoA in covalent bonding

A

Strong electrostatic forces of attraction between positively charged nuclei of two atoms and shared pair of electrons

21
Q

Describe the FoA in metallic bonding

A

Strong electrostatic forces of attraction between lattice of positive metal ions and sea of delocalised electrons

22
Q

In giant covalent structures, what type of bonds must be overcome to melt or boil the substances?

A

The strong covalent bonds that all of the atoms in the structure are linked to each other by

23
Q

What are carbon nanotubes?

A

Cylindrical fullerenes with very high length to diameter ratio

24
Q

How big are nanoparticles?

A

Diameter between 100 and 2500 nm, structures of around a few hundred atoms

25
Disadvantages of nanoparticles?
Health risks (can be toxic), environmental impact, long term side effects unknown
26
Why might it not be possible to obtain the calculated amount of a product?
The reaction may not go to completion because it is reversible Some of the product may be lost when separated from the reaction mixture Some of the reactants may react in ways different to the expected reaction
27
What is the volume of one mole of any gas at room temp?
24dm^3
28
The reactivity of a metal with water or dilute acids depends on what?
How easily it loses electrons to form its positive ion
29
Why is carbon used as the anode in electrolysis of aluminium oxide
Good conductor and can withstand high temperatures
30
Is cryolite a catalyst?
NO - it does not provide an alternative reaction pathway with a lower activation energy, and it gradually breaks down. It acts more like a solvent to lower the melting point of AlO2 - physical function not chemical
31
What is the half equation for the cathode when hydrogen ions are reduced?
2H+ + 2e- → H2
32
What is the half equation for the anode when hydroxide ions are oxidised?
4OH- → O2 + 2H2O + 4e-
33
The half-equation at the cathode during the electrolysis of aluminium oxide?
Al3+ + 3e− → Al
34
The half-equation at the anode during the electrolysis of aluminium oxide?
2O2− → O2 + 4e−
35
Balanced equation for aluminium oxide electrolysis?
2Al2O3 → 4Al + 3O2 ​
36
Why can some cells and batteries be recharged?
Rechargeable cells and batteries can be recharged because the chemical reactions can be reversed when an external electrical current is supplied.
37
What is the half equation for a hydrogen fuel cell's anode?
H2 → 2H+ + 2e−
38
What is the half equation for a hydrogen fuel cell's cathode?
O2 + 4H+ + 4e− → 2H2O