Chemical kinetics Flashcards

1
Q

The study of reaction rates defined by the change in the concentrations of
reactants and products with time.

A

Chemical kinetics

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2
Q

The __________ in a rate law describe the mathematical
dependence of the rate on reactant concentrations.

A

Reaction Order

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3
Q

is simply the sum of orders for each
reactant.

A

overall reaction order

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4
Q

of a reaction is the instantaneous rate at the
start of the reaction (when t = 0).

A

initial rate

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5
Q

A state in the course of a reversible chemical reaction in which no
net change in the amounts of reactants and products occurs.

A

CHEMICAL EQUILIBRIUM

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6
Q

is one in which the products, as soon
as they are formed, react to produce the original reactants.

A

reversible chemical reaction

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7
Q

At equilibrium, the two opposing reactions go
on at equal rates, or velocities, and hence
there is _________ in the amounts of
substances involved.

A

no net change

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8
Q

At this point the reaction
may be considered to be completed

A

CHEMICAL EQUILIBRIUM

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9
Q

Acids and bases have a chemical equilibrium in solution. At chemical
equilibrium, the products and reactants have reached a state of _______

A

balance

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10
Q

Any compound that can transfer a proton to any other compound is an acid,
and the compound that accepts the proton is a base.

A

Bronsted Lowry Theory:

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11
Q

a substance can function as an
acid only in the presence of a base;
similarly, a substance can function as a
base only in the presence of an acid.

A

Brønsted-Lowry
scheme

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12
Q

when an acidic substance
loses a proton, it forms a base, called
the __________ of an acid,

A

Conjugate base

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13
Q

when a basic substance gains a proton,
it forms an acid called the ___________

A

conjugate
acid of a base.

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14
Q

Determining the acid base equilibrium can help in predicting the products of a
reaction and the relative concentration of the products, as well as aiding in the

A

Identification of the weaker acid and base

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15
Q

______ Bronsted-Lowry acid are those which have a strong tendency to give a
proton and their corresponding conjugate base is weak.

A

Strong

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16
Q

_______ Bronsted-Lowry acids will have a little tendency to donate a proton and
their corresponding conjugated base is strong.

A

weak

17
Q

Acids are substances that dissociate in water to yield electrically charged atoms
or molecules, called ions, one of which is a hydrogen ion (H+

), and that bases

ionize in water to yield hydroxide ions (OH−
).

A

Arrhenius Theory:

18
Q

Acids are substances that dissociate in water to yield electrically charged atoms
or molecules, called ions, one of which is a hydrogen ion (H+

), and that bases

ionize in water to yield hydroxide ions (OH−
).

A

Arrhenius Theory:

19
Q

Limitations of Arrhenius theory

A

The Arrhenius theory is applicable only in aqueous solution;

20
Q

for example,
according to the theory, HCl is an acid in the aqueous solution but not in
benzene, even though it donates the H+ ion to the benzene. Also, under
Arrhenius’s definition, the solution of sodium amide in liquid ammonia is not
alkaline, even though the amide ion deprotonates the ammonia.

A

The Arrhenius theory is applicable only in aqueous solution;

21
Q

In the Lewis theory of acid-base reactions, ______ donate pairs of electrons and
acids accept pairs of electrons.

A

bases

22
Q

One way to determine the pH of a buffer
is by using the __________
equation, which is pH = pKa +
log([A−]/[HA]).

A

Henderson-Hasselbalch Equation:

23
Q

[HA] and [A−] refer to
the equilibrium concentrations of the
conjugate acid–base pair used to create
the buffer solution.

A

Henderson-Hasselbalch Equation:

24
Q

State the Henderson-Hasselbalch equation

A

**check notes

25
Q

Increases the concentration of hydrogen ions in an aqueous solution

A

Arrhenius acid

26
Q

Increases the concentration of hydroxide ions in an aqueous solution

A

Arrhenius base

27
Q

any substance, such as the H+

ion, that can accept a
pair of nonbonding electrons.

A

Lewis acid

28
Q

is an electron-pair
acceptor.

A

Lewis acid

29
Q

is any substance, such as the OHion, that can donate a
pair of nonbonding electrons.

A

Lewis base

30
Q

therefore an electron-pair donor.

A

Lewis base