Chemical Reactions part 1 Flashcards

1
Q

Define chemical change

A

Reactants -> Products
Products have different properties to the reactants
Most are irreversible
Eg. Combustion reaction

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2
Q

Define physical change

A

The substance itself does not change, it just takes on a different form
Eg. Phase/State changes

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3
Q

Define rate of reaction

A

The change in concentration per unit of time of either the product or the reactant

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4
Q

Define collision theory

A

A reaction will only occur when an effective collision takes place. The more effective collisions take place per unit time, the faster the rate of reaction.

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5
Q

What are the 5 factors that affect the rate of reaction? Explain each.

A
  1. Increase concentration - Liquids
    Increase number of particles, therefore increase number of collisions
  2. Increase temperature
    Particles have more energy -> Move faster -> More frequent collisions -> collisions have more energy
  3. Decrease volume / Increase pressure - Gases
    Particles are closer together, more collisions
  4. Catalyst
    Lowers activation energy
  5. Increase surface area - solids
    More area for particles to collide with, therefore more collisions
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6
Q

Explain temperature as a factor of affecting the rate of reaction.

A

As temperature increases, particles gain kinetic energy and move faster; which results in:
More collisions per second
More of the colliding particles have sufficient energy to react
Temp up, Rate of reaction up

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7
Q

Explain concentration as a factor of affecting the rate of reaction.

A

The higher the concentration, the more particles per unit volume
Results in more effective collisions per unit time and a faster reaction rate.

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8
Q

Explain catalyst as a factor of affecting the rate of reaction.

A

Def: A catalyst increases the rate of reaction and is unchanged at the end of the reaction
Mechanism: The catalyst decreases the activation energy of the reaction
Result: More collisions with be effective as more molecules collide with equal to or greater than the activation energy
More effective collisions lead to a faster reaction rate.

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9
Q

Explain surface area as a factor of affecting the rate of reaction.

A

Smaller the particle size -> greater surface area eg. powder vs chunks
Greater the surface area -> More surface exposed for the reaction to take place
Results in more effective collisions per unit time

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10
Q

Explain pressure as a factor of affecting the rate of reaction.

A

Increase pressure by reducing volume -> reduce space in which the gas particles can move
Results in more effective collisions per unit time and a faster reaction rate

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11
Q

What are the 2 methods of measuring the rate of reaction?

A
  1. Measure the volume of gas given off every minute
  2. Measure the decrease in mass of the reactant as the gas escapes
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