chemical_changes Flashcards

(52 cards)

1
Q

Oxidation

A

When a substance gains oxygen

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2
Q

Reduction

A

When a substance loses oxygen

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3
Q

Reactivity series of metals

A

The series shows the metals in order of their reactivity.

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4
Q

Reactivity with acids

A

Metals above H2 in reactivity series react with acid to produce H2.

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5
Q

Reactivity trends

A

The more reactive the metal is

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6
Q

Metals below H2

A

Metals below H2 don’t react with acids.

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7
Q

Unreactive metals in Earth

A

In their natural state (well

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8
Q

Extraction of metals less reactive than carbon

A

Reduction with carbon. Carbon displaces the metal in a metal oxide - gets oxidised to carbon oxides. Metal from the metal oxide gets reduced to the pure metal.

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9
Q

Extraction of metals more reactive than carbon

A

By electrolysis

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10
Q

Oxidation in terms of electron transfer

A

Loss of electrons

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11
Q

Reduction in terms of electron transfer

A

Gain of electrons

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12
Q

General equation for reaction between metals and acids

A

Metal + acid → salt + hydrogen

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13
Q

Type of reaction between metals and acids

A

Redox reaction

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14
Q

Metals that react with acid

A

Those above hydrogen

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15
Q

General equation for a neutralisation reaction

A

Base + acid → salt + water

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16
Q

General equation for reaction between metal carbonate and acid

A

Metal carbonate + acid → salt + water + carbon dioxide

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17
Q

General equation for reaction between metal oxides and acids

A

Metal oxide + acid → a salt + water

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18
Q

Redox reaction

A

A reaction that involves both oxidation and reduction.

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19
Q

Redox Reaction

A

A reaction where both oxidation and reduction occurs.

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20
Q

Oxidation of Magnesium

A

Magnesium has lost electrons and thus has been oxidised (Mg to Mg2+).

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21
Q

Reduction of Hydrogen

A

The hydrogen in HCl has gained electrons and thus has been reduced (H+ to H2).

22
Q

Formation of Soluble Salt

A

React the excess acid with some insoluble chemical (e.g. metal oxide)

23
Q

Products of Acids and Alkalis

A

Acids produce hydrogen ions

24
Q

Definition of Bases

25
pH Scale
The measure of acidity/alkalinity of a solution; neutral solution.
26
Neutralisation Reaction Equation
H+ + OH− → H2O.
27
Strong Acid
Strong acid is completely ionised in aqueous solution.
28
Weak Acid
Weak acid is only partially ionised in aqueous solution.
29
Effect of H+ Concentration on pH
The pH decreases as the concentration of H+ increases.
30
Concentrated Acid
Concentrated acid has more moles of acid per unit volume than dilute.
31
Dilute Acid
Dilute refers to solutions of low concentrations.
32
Strength vs Concentration of Acids
It is not the same - concentration is not the same thing as strength of an acid. Strength refers to whether the acid is completely ionised in water (strong) or only partially (weak).
33
Change in H+ Concentration with pH
As the pH is decreased by one unit
34
LiNO3
Lithium nitrate
35
K2CO3
Potassium carbonate
36
MgBr2
Magnesium bromide
37
BaSO4
Barium sulfate
38
Electrolysis
The passing of an electric current through ionic substances that are molten or in solution to break them down into elements; ions are discharged (they lose/gain electrons) at electrodes to produce these.
39
Electrolyte
The liquid/solution which conducts electricity.
40
Cathode
The negative electrode.
41
Anode
The positive electrode.
42
Reduction at the Cathode
Reduction occurs at the cathode.
43
Oxidation at the Anode
Oxidation occurs at the anode.
44
Discharged Element at Cathode
The less reactive element discharges at the cathode. Hydrogen is produced unless there is a less reactive metal
45
Oxygen Production at Anode
Oxygen is produced at the anode unless the solution contains halide ions
46
Aluminium Manufacturing
Aluminium is made through the electrolysis of aluminium oxide and cryolite.
47
Cost of Aluminium Production
Lots of energy is needed to produce the current in electrolysis which makes this process expensive.
48
Half Equations in Aluminium Extraction
Al3+ + 3 e− → Al (cathode); 2 O2− → O2 + 4 e− (anode). Oxygen reacts with C of the anode producing CO2.
49
Cryolite Usage
It lowers the melting point of aluminium oxide
50
Half Equations in Electrolysis of Aqueous Na2SO4
2 H+ + 2 e− → H2 (cathode); 4 OH− → 2 H2O + O2 + 4 e− (anode).
51
Half Equations in Electrolysis of Molten and Aqueous KCl
K+ + e− → K (cathode); 2 Cl− → Cl2 + 2 e− (anode). 2 H+ + 2 e− → H2 (cathode); 2 Cl− → Cl2 + 2 e− (anode)
52
Half Equations in Electrolysis of Aqueous CuBr2
Cu2+ + 2 e− → Cu (cathode); 2 Br− → Br2 + 2 e− (anode).