organic chem Flashcards

(49 cards)

1
Q

Crude oil

A

Crude oil is a mixture of compounds; a fossil fuel consisting of the remains of ancient biomass. Finite resource - cannot be replaced as it is used up.

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2
Q

Hydrocarbon

A

A compound made up exclusively of hydrogen and carbon atoms.

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3
Q

Alkanes

A

Saturated hydrocarbons of a general formula CnH2n+2.

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4
Q

Homologous series

A

Series of compounds with same general formula

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5
Q

Combustion of hydrocarbons

A

Exothermic reaction occurring when hydrocarbons are reacted with oxygen. Complete combustion produces carbon dioxide and water (carbon and hydrogen atoms are completely oxidised). Incomplete combustion produces carbon or carbon monoxide and water.

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6
Q

Physical properties of alkanes

A

First few in series are gases

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7
Q

Fractional distillation of crude oil

A

Crude oil is heated and vaporised. Vapor rises up the fractionating column (tower). The column is hotter at the bottom and cooler at the top. Hydrocarbons cool as they go up the column and condense at different heights

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8
Q

Cracking

A

When large hydrocarbons are thermally broken down into smaller and useful molecules.

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9
Q

Type of reaction for cracking

A

Thermal decomposition.

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10
Q

Conditions for cracking

A

Reactant heated to vapor

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11
Q

Products of cracking

A

The products are alkanes and alkenes - used as polymers and starting materials for synthesis.

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12
Q

Alkene

A

Unsaturated hydrocarbon. Contains a C=C bond. General formula for alkenes is: CnH2n.

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13
Q

Test for alkenes

A

Add bromine water. Colour change occurs from orange to colourless.

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14
Q

Combustion of alkenes

A

They burn with smoky flames due to incomplete combustion.

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15
Q

Addition reactions of alkenes

A

Addition atoms across the carbon-carbon double bond so that the double bond becomes a single carbon-carbon bond.

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16
Q

Hydrogenation

A

Addition of hydrogen; requires a higher temperature and a nickel catalyst.

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17
Q

Hydration

A

Addition of steam; requires high temperature

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18
Q

Addition of halogens

A

Addition of Br2/Cl2/I2.

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19
Q

Alcohol

A

An organic compound that contains an -OH functional group.

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20
Q

Characteristics of methanol

21
Q

Oxidation of alcohols

A

Leads to carboxylic acids.

22
Q

Uses of alcohols

A
  • Fuels - Solvents - Drinks
23
Q

Conditions for fermentation of glucose

A

30 degrees Celsius

24
Q

Equation of fermentation of glucose

A

C6H12O6 → 2 CH3CH2OH + 2 CO2.

25
Carboxylic acids
Organic compounds that contain a COOH functional group.
26
Characteristics of carboxylic acids
- Dissolve in water to form an acidic solution (contains H+ ions) - React with metal carbonates to form carbon dioxide - React with alcohols with an acid catalyst to produce esters - React with metals to give off hydrogen gas.
27
Type of acid is carboxylic acid
It is a weak acid.
28
Why carboxylic acids are weak acids
They are partially dissociated in water
29
Ester
An organic compound containing a -COO- functional group
30
Characteristics of esters
They have a fruity smell.
31
Polymer
A substance formed from many repeating units
32
Polymer
A long chain molecule which is made by lots of smaller molecules joining together.
33
Addition polymerisation
A reaction where C=C bonds open up and many smaller molecules (monomers) join together to form a chain (a polymer). No other products are made.
34
Polyethene
A type of addition polymer used for plastic bags.
35
PTFE
(Poly)tetrafluoroethene
36
PVC
(Poly)chloroethene
37
Repeating unit of a polymer
The smallest structure which
38
Condensation polymer
A polymer made in condensation polymerisation
39
Polyester
An example of a condensation polymer
40
Polyamide
An example of a condensation polymer
41
Amide bond
A bond similar to the ester bond
42
Amino acid
An organic compound that contains both a carboxylic acid functionality (COOH) and an amine functional group (-NH2).
43
Proteins
Polymers made of amino acids (monomers) formed by numerous condensation polymerisation reactions.
44
Polypeptides
Chains made by condensation polymerisation of amino acids
45
Carbohydrates
Organic molecules made of C
46
Starch
A polymer made of glucose monomers.
47
Cellulose
A polymer made of glucose monomers
48
DNA
Deoxyribonucleic acid
49
DNA structure
Made of two polymer chains held together in a double helix