organic chem Flashcards
(49 cards)
Crude oil
Crude oil is a mixture of compounds; a fossil fuel consisting of the remains of ancient biomass. Finite resource - cannot be replaced as it is used up.
Hydrocarbon
A compound made up exclusively of hydrogen and carbon atoms.
Alkanes
Saturated hydrocarbons of a general formula CnH2n+2.
Homologous series
Series of compounds with same general formula
Combustion of hydrocarbons
Exothermic reaction occurring when hydrocarbons are reacted with oxygen. Complete combustion produces carbon dioxide and water (carbon and hydrogen atoms are completely oxidised). Incomplete combustion produces carbon or carbon monoxide and water.
Physical properties of alkanes
First few in series are gases
Fractional distillation of crude oil
Crude oil is heated and vaporised. Vapor rises up the fractionating column (tower). The column is hotter at the bottom and cooler at the top. Hydrocarbons cool as they go up the column and condense at different heights
Cracking
When large hydrocarbons are thermally broken down into smaller and useful molecules.
Type of reaction for cracking
Thermal decomposition.
Conditions for cracking
Reactant heated to vapor
Products of cracking
The products are alkanes and alkenes - used as polymers and starting materials for synthesis.
Alkene
Unsaturated hydrocarbon. Contains a C=C bond. General formula for alkenes is: CnH2n.
Test for alkenes
Add bromine water. Colour change occurs from orange to colourless.
Combustion of alkenes
They burn with smoky flames due to incomplete combustion.
Addition reactions of alkenes
Addition atoms across the carbon-carbon double bond so that the double bond becomes a single carbon-carbon bond.
Hydrogenation
Addition of hydrogen; requires a higher temperature and a nickel catalyst.
Hydration
Addition of steam; requires high temperature
Addition of halogens
Addition of Br2/Cl2/I2.
Alcohol
An organic compound that contains an -OH functional group.
Characteristics of methanol
ethanol
Oxidation of alcohols
Leads to carboxylic acids.
Uses of alcohols
- Fuels - Solvents - Drinks
Conditions for fermentation of glucose
30 degrees Celsius
Equation of fermentation of glucose
C6H12O6 → 2 CH3CH2OH + 2 CO2.