Chemistry In Industry (Cracking, Crude Oil, Polymers, Haber Process) Flashcards

(46 cards)

1
Q

What is cracking

A

Splitting up long chain hydrocarbons

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2
Q

Longer hydrocarbons have _________ boiling points and are _______ viscous. They are also thicker and __________ in colour

A

Higher
More
Darker

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3
Q

Why do we crack

A

Because demand for short chain hydrocarbons is much higher

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4
Q

Cracking:
Temperature:
Catalysts needed:

A

Temperature: 600-700C

Catalyst needed: Silica and alumina

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5
Q

What is crude oil

A

A mixture of hydrocarbons

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6
Q

From top to bottom: What are the fractions formed from crude oil

A
Refinery gases
Gasoline
Naphtha
Kerosene
Diesel
Fuel oil
Bitumen
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7
Q

How does fractional distillation of crude oil work

A

Oil is heated
Gases evaporate
When the temperature becomes lower than their boiling point, the gases condense

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8
Q

What is the purpose of bubble caps

A

To prevent liquids from running back down

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9
Q

As you go up, the fractions get:
_______ viscous
________ flammable
_________ boiling points

A

Less viscous
More flammable
Lower boiling points

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10
Q

Use of:

Refinery gases

A

Heating

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11
Q

Use of:

Gasoline

A

Fuel for cars

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12
Q

Use of:

Naphtha

A

Plastics

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13
Q

Use of:

Kerosene

A

Jet engines

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14
Q

Use of:

Diesel

A

Fuel for diesel engined cars, trucks etc.

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15
Q

Use of:

Fuel oil

A

Domestic central heating

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16
Q

Use of:

Bitumen

A

Road surfacing

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17
Q

What may incomplete combustion of fuel produce

A

Carbon monoxide

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18
Q

In car engines, the temperature is high enough for what to happen

A

Nitrogen and oxygen to react forming nitrogen oxides

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19
Q

Nitrogen oxides and sulfur dioxides are pollutant gases which contribute to what?

20
Q

What is an addition polymer formed by

A

Many small molecules called monomers

21
Q

What are the 2 types of polymer

A

Addition polymers

Condensation polymers

22
Q

Under _______ pressure and a catalyst, alkenes will open up their double bonds and join together to form __________. What is this is known as

A

High
Polymers
Addition polymerisation

23
Q

What is condensation polymerisation

A

When different types of polymer react together and bonds form between them, making polymer chains

24
Q

For each new bond that forms in condensation polymerisation, a small molecule (e.g _______) is lost

25
Name an example of a condensation polymer
Nylon
26
Name a use for poly(ethene)
Plastic bags
27
Name a use for poly(propene)
Carpets
28
Name a use for poly(chloroethene)
Clothes, pipes
29
What is a problem with polymers due their inertness
Since they are inert, they don't react. They are hard to get rid of
30
It takes a very _______ time for polymers to biodegrade
Long
31
What does biodegrade mean
Be decomposed by bacteria
32
The haber process produces __________ which is used to make __________
Ammonia | Fertilisers
33
Which two elements are used to make ammonia
Nitrogen and Hydrogen
34
Where is nitrogen obtained from
The air
35
Where is hydrogen obtained from
Natural gas, or cracking
36
Conditions for haber process: Temperature: Pressure: Catalyst:
Conditions for haber process: Temperature: 450C Pressure: 200atmospheres Catalyst: Iron
37
Higher pressures favour the forward reaction, so the pressure is made as _______ as possible without making the plant too expensive to build
High
38
In the haber process, the forward reaction is ______thermic
Exothermic
39
What does increasing the temperature do to the equilibrium
Moves it the wrong way - Away from the ammonia and towards the N2 and H2
40
Why do we increase the temperature a bit even though increasing the temperature would move the equilibrium the wrong way,
Because increasing the temperature also increases the rate of reaction. 450C is a comprimise
41
The ammonia is formed as a _______
Gas
42
What happens when the ammonia cools in the condenser
It liquefies and is removed
43
What happens to the unused hydrogen and nitrogen
It is recycled so nothing is wasted
44
What can ammonia be used for
Fertilisers
45
Ammonia can be used to make nitric acid, what do you get if you react ammonia with nitric acid
Ammonium nitrate
46
Why is ammonium nitrate a particularly good fertiliser
Because it contains nitrogen from two sources