Physical Chemistry (Acids, Alkalis, Salts, Energetics, Rates Of Reaction, Equilibria) Flashcards

(42 cards)

1
Q

Universal indicator:
Acid:
Neutral:
Alkali:

A
Strongly acidic: Red
Weakly acidic: Orange
Neutral: Green
Weakly alkali: Blue
Strongly alkali: Purple
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Litmus paper:
Acid:
Neutral:
Alkali:

A

Acid: Red
Neutral: Purple
Alkali: Blue

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Phenolphthalein:
Acid:
Alkali:

A

Acid: Colourless
Alkali: Pink

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Methyl Orange:
Acid:
Alkali:

A

Acid: Red
Alkali: Yellow

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Ph 0 =

A

Strongly acidic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Ph 14 =

A

Strongly acidic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

An acid is a source of ____________ ions

A

Hydrogen ions (H+)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

An alkali is a source of ____________ ions

A

Hydroxide ions (OH-)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

The reaction between an acid and an alkali (or an acid and a base) is known as:

A

Neutralisation

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Acid + Base–>

A

Acid + Base–> Salt + Water

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Acid + Metal Oxide–>

A

Acid + Metal Oxide–> Salt + Water

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Acid +Metal Carbonate –>

A

Acid +Metal Carbonate –> Salt + Water + Carbon dioxide

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

If the acid is hydrochloric acid, the salt will be a metal ___________

A

Chloride

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

If the acid is sulfuric acid, the salt will be a metal ___________

A

Sulfate

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

If the acid is nitric acid, the salt will be a metal ___________

A

Nitrate

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Everything is soluble except for:

A

Carbonates (Except for sodium potassium and ammonium)
Barium sulfate
Calcium sulfate
Silver chloride

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

How do you make a soluble salt using acids

A

Add an insoluble base

18
Q

Describe making a soluble salt using acids + insoluble bases

A

Add the insoluble base to the acid. The solid will dissolve. The acid had neutralised when the excess solid sinks to the bottom of the flask.
You can then filter out the excess solid to get the salt solution.
For pure, sold crystals of salt, evaporate off the water.

19
Q

How do you make soluble salts from an alkali

20
Q

How do you make insoluble salts

A

Precipitation reaction

21
Q

Describe a precipitation reaction:

A

Pick two solutions with the ions you need and mix them

22
Q

How do you do a titration

A
  1. Add (25cm3 of) alkali to a conical flask alongside indicator
  2. Meanwhile, fill a burette with acid (below eye level)
  3. Add the acid to the alkali (using a burette)
  4. The indicator will change colour when neutralisation takes place
  5. Record the volume of acid used to neutralise the alkali
  6. Repeat
23
Q

What four things does a rate of reaction depend on:

A

Temperature
Concentration (pressure)
Catalyst
Size of particles (surface area)

24
Q

Rate of reaction equation

A

Rate of reaction = amount of product formed (or reactant used) / Time

25
What are the 3 ways the speed of reaction can be measure
Precipitation Change in mass Volume of gas given off
26
How does a catalyst speed up a reaction
By providing an alternative pathway with lower activation energy
27
What is activation energy
The minimum energy needed by reacting particles for the reaction to occur
28
Chemical reactions in which heat is given out are known as ______________
Exothermic
29
Chemical reactions in which heat is taken in are known as ______________
Endothermic
30
Energy is _____________ to break existing bonds - so bond breaking is an _____________ process
Supplied | Endothermic
31
Energy is _____________ when new bonds are formed - so bond formation is an _____________ process
Released | Exothermic
32
If the value of enthalpy change is negative, the reaction is ______thermic
Exothermic
33
If the value of enthalpy change is positive, the reaction _____thermic
Endothermic
34
In an exothermic energy level diagram, the reactants are __________ the products
Above
35
In an endothermic energy level diagram, the reactants are __________ the products
Below
36
What is a reversible reaction
Where the products of the reactions can themselves react to produce the original reactants
37
Describe the thermal decomposition of ammonium chloride
When heated, ammonium chloride breaks down into ammonia and hydrogen chloride. When the ammonia and hydrogen chloride cool, they re-form to make ammonium chloride
38
What does equilibrium mean
That the relative quantities of reactants and products will reach a certain balance and stay there
39
In a reversible reaction, the position of equilibrium depends on the ____________ and ____________ of the reacting mixture
Temperature and pressure
40
What is the effect of increasing temperature on equilibrium. | What is the effect of decreasing temperature on equilibrium
If you increase the temperature, endothermic reaction will increase (to use up extra heat) If you decrease the temperature, exothermic reaction will increase (to give out more heat)
41
What is the effect of increasing pressure on equilibrium | What is the effect of decreasing pressure on equilibrium
If you increase the pressure, it will encourage the reaction which produces fewer molecules of gas If you decrease the pressure, it will encourage the reaction which produces more molecules of gas
42
What is dynamic equilibrium
The reactions are still taking place in both directions, but the overall effect is nil because they cancel each other out