Class Three Flashcards

(55 cards)

1
Q

key property of a physical change

A

no intramolecular bonds are broken - only affects intermolecular forces

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2
Q

temperature is a measure of the amount of internal ___ energy

A

kinetic

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3
Q

kinetic energy of molecules directly affects its ____

A

phase

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4
Q

the higher the average kinetic energy..

A

the higher its entropy

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5
Q

fusion phase change

A

solid → liquid

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5
Q

fusion phase change

A

solid → liquid

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6
Q

crystallization phase change

A

liquid → solid

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7
Q

sublimation phase change

A

solid → gas

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8
Q

deposition phase change

A

gas → solid

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9
Q

heat of transition

A

amount of energy required to complete a phase transition

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10
Q

heat of transition formula

A

q = n x change in H

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11
Q

1 cal =

A

4.2 J

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12
Q

when a substance absorbs or releases heat, 1 of 2 things can occur..

A

either temperature changes OR it will undergo a phase change

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13
Q

heat capacity formula

A

q = mc(change in T)

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14
Q

what is a substance’s specific heat

A

intrinsic property → tells us how resistant it is to changing temperature

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15
Q

during a phase transition.. (temp)

A

the temperature of the substance does not change

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15
Q

during a phase transition.. (temp)

A

the temperature of the substance does not change

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16
Q

triple point

A

the temperature & pressure at which all 3 phases exist in equilibrium

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17
Q

critical point

A

marks the end of the liquid-gas boundary

after this, substances display properties of liquids & gases aka supercritical fluid

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18
Q

what makes water special

A

denser in liquid form vs solid

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19
Q

increasing pressure on ice..

A

turns into liquid (ice skating)

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20
Q

what is vapour pressure

A

force exerted by the gas particles

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21
Q

boiling point is when..

A

vapour pressure = atmospheric pressure

22
Q

why do the molecules of gas essentially take up no colume

A

they’re so small compared to the space in between them

23
what defines the pressure of a gas
the collisions of the molecules with the walls of the container
24
kelvin to celsius
C + 273 = K
25
pascal to atm
100 kPa = 1 atm
26
atm to torr
1 atm = 760 torr
27
ideal gas law formula
PV = nRT
28
Charle's law
if pressure is constant, gas will expand when heated & contract when cooled volume is proportional to temperature
29
Boyle's law
if temperature is constant, as volume decreases → pressure increases volume and pressure are inversely related
30
combined gas law formula
31
Avogadro's Law
equal pressure, volume and temp = then the two have the same # of particles
32
main assumptions for kinetic-molecular theory (2)
particles of an ideal gas experience no intermolecular forces volume of individual particles of an ideal gas can be ignored compared to the volume of the gas container
33
what equation is used for real gases (do not behave as ideal gases)
van der Waals equation
34
van der Waals formula
35
when does the deviation from ideal gas law become more pronounced
with gases with stronger intermolecular forces
36
what makes a good ideal gas
low molecular weight & weak intermolecular forces
37
Dalton's law of partial pressures
total pressure is the sum of partial pressures of all the gases in a mixture
38
what is effusion
the escape of a gas molecule through a tiny hole
39
Graham's law of effusion
where r = rate of effusion and M = molar mass
40
what is rms
average speed of molecules
41
avg kinetic energy and temp relationship
they are directly proportional
42
the solvent is usually..
water
43
what is a strong electrolyte
something that will dissociate 100%
44
van't Hoff factor
number of particles produced in a solution per mole of substance
45
how do electrolytes dissociate into water
agitation (endo) → dissociation (endo) → solvation (exo)
46
how do polar non-electrolytes dissociate in water
agitation → solvation
47
how do non-polar non electrolytes dissociate in water
it doesn't lol
48
unsaturated solution
concentration is less than solubility
49
saturated solution
concentration = solubility
50
supersaturated solution
concentration is greater than solubility
51
when is solubility indirectly proportional to temp
gas solutes in water
52
always soluble electrolytes in water
group 1 ions, H+, NH+. NO3-
53
not soluble electrolytes in water
transition metals PO4-