Clinical aspects of amalgam Flashcards
(41 cards)
Define amalgam
an alloy of silver, mercury and tin with other metals added to change the properties
What makes the amalgam paste?
alloy powder + liquid mercury -> mouldable paste for few mins
Describe the amalgam capsules
sealed by law
contains liquid mercury in one end and alloy powder in the other
prevented from mixing by thin membrane that gets broken when plunger is pressed
mixed at high speed in amalgamator
What are the 2 shapes of the allow powder particles?
spherical
lathe-cut
Describe spherical particles
Made by spraying molten metal into a fine mist.
Softer, more flowable – easier to pack into cavity.
Describe lathe-cut particles
Made by creating an ingot of alloy and grinding it down into a powder.
Less flowable, good for building up large amounts of missing tooth structure.
What happens when the alloy powder dissolves in liquid mercury?
mercury dissolves powder
powder mainly contains silver and tin
silver and tin goes out into solution and ends up with solution containing mercury, tin and silver
What are the 3 different phases that occur when metals in amalgam dissolve?
gamma phase - silver-tin Ag-Sn
gamma-1 phase - silver-mercury Ag2Hg3
gamma-2 phase - tin-mercury Sn8Hg
Describe gamma phase Ag3Sn
the strongest phase
provides high mechanical durability
resistant to wear and fracture
Describe gamma-1 phase Ag2Hg3
moderate strength, weaker than gamma phase
plays a role in binding amalgam together
Describe gamma-2 phase Sn8Hg
unwanted product
poor mechanical properties
causes…
- corrosion
- creep
- decreased strength
main cause of amalgam failure
What metal reduces gamma-2 phase?
copper
they can either reduce or eliminate this phase, improving longevity
Define creep
The slow deformation of a dental material when exposed to long-term stress, such as chewing forces.
What are the causes of creep?
weak structure due to presence of gamma-2 phase
continuous pressure from biting and chewing
What are the effects of creep?
restoration gradually distorts
can lead to fractures and failure over time
weakens the margins of filling, allowing bacteria to enter
What is corrosion?
a chemical reaction where the metal in amalgam degrades over time.
What are the causes of corrosion?
saliva (electrochemical reactions)
bacteria and acids in the mouth
contact with other metals in the mouth (eg gold crowns)
What are the negative effects of corrosion?
weakens amalgam, leading to failure
rough surfaces that trap plaque and bacteria
secondary caries
gamma-2 phase is highly prone to corrosion
What is the positive effect of corrosion?
corrosion products fill gaps between amalgam and dentine
this prevents micro leakage, stopping bacteria from entering
helps reduce sensitivity by blocking tiny openings
What is the typical composition by % wt of a modern-day amalgam?
silver - 65
tin - 29
copper - 6-13
zinc - 2
Why is zinc put in amalgam?
prevents silver from oxidising during powder manufacture
acts as oxygen scavenger
no direct benefit to material
not necessary if manufactured in vacuum
What can zinc cause during setting?
excessive expansion
What are the issues if the mercury content is too low?
too dry and unworkable
if <50% mercury
What happens if the mercury content is over 50%?
needed for workability
but weakens amalgam over time