composites Flashcards
(35 cards)
What are the 6 definite advantages of resin composites?
- esthetic colors and shades
- direct intraoral application possible
- insulation of the pulp against sensitivity to heat and cold
- do not corrode or dissolve
- adhesive to acid-etched enamel
- adhesive to dentin when combined with a dentin bonding material
what are the 6 variable advantages of resin composites?
- polishable to an excellent smoothness
- comparatively strong and wear resistant
- acceptable color stability
- resistant to water softening and dissolution
- can be made radiopaque for better diagnostic utility by addition of heavy-metal-containing fillers
- can be used for class 1,2,3 and 5 restorations where there is a stress involved
what are the 6 disadvantages of resin composites?
- still too much polymerization shrinkage/shrinkage stress although much reduced over unfilled acrylic restoratives
- incomplete curing
- mismatch between the thermal expansion/contraction of the resin and tooth
- marginal leakage of soluble components left from incomplete curing can leach and cause inflammation and/or sensization
- degrade by hydrolysis and esterases
- wears more than amalgam
megafill
0.2-0.5 mm
macrofill
10-100 nm
midfill
1-10 nm
minifill
0.1-1 nm
microfill
0.01-0.1 nm
nanofill
0.005-0.01nm
hybrid
microfill + larger fillers
optimal size
higly fillable and polishable point 4- kerr, esthet-x-caulk
function of filler
- strrnghten and partially replace the matrix material
- reinforce- increase hardness, strength and wear resistance.
- offset polymerization shrinkage
- control workability- liquid monomer+filler=paste < the more filler the the thicker the paste
- reduce thermal expansion and contraction
- decrease water sorption> less softening and less staining
- Impart radiopacity- adequate for diagnostic purposes
function of matrix
add rigidity and strength- cross-linked polymer structure
reduce polymerization shrinkage
function of coupling agent
adheres matrix to the filler particles
Bis-Gma
main component of matrix in the vast majority of dental restoratives in europe UDMA
TEGMA
dilute the matrix to gain a more workable consistency
3-methacryloxy-propyltrimethoxysilane
form a chemical interfacial bond between filler and polymer matrix- it is a coupling agent
dimethyl amine ethylmethylamine
form a free radical initiating the reaction
EDMAB
form a free radical initiating the reaction
what are the methods used to develop bulk fill composites
- match the indices of refraction of the filler and the resin< when the index of refraction matches less light is scattered, transparency is increased, and more light can penetrate
- low-color initiators are being sed to reduce the color of the composite and allow more light to be transmitted
- dual-cure initiators can be used to give unlimited depth of cure
what are the the methods used to develop low shrinkage in composites
- particle size distribution of the filler is tightly controlled to produce a very highly filled composite
- Oxirane monomers open their aromatic rings and expand to form chemical bonds- you can reduce shrinkage even more by mixing in other expanding monomers
- flexible methacrylate end groups that provide a rod-like shape that facilitates assembly into compact structures- combined with dilution of polymerizable end groups reduce shrinkage
- reactive ends are long and provide a double bond dilution- also, hydrophobic center restricts water absorption and solubility - leads to formation of 2 separate phases during polymerization and a small expansion
unique properties of copomers
compared to resin- include reaction, ion-leachable glass particles and polymerizable acidic monomers
compared to hybrid they have larger filler particles and do not polish as well
how are microfillers produced?
cured and then pulverized to make a filled resin powder
what are the advantages of a hybrid composite?
restoring stress prone sites where esthetic considerations dominate