EL8:1 Spectacular Metals Flashcards

1
Q

What are the most reactive metals in the periodic table?

A

Group 1 and 2.

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2
Q

What are group 1 metals called?

A

Alkali metals.

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3
Q

What are group 2 metals called?

A

The alkaline earth metals.

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4
Q

What happens as you go down groups in the periodic table?

A

Elements get more metallic and therefore get more reactive.

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5
Q

What happens as you go across a periods in the periodic table?

A

Elements become less metallic.

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6
Q

What block are groups 1 and 2 in?

A

The s block.

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7
Q

What do s block metals tend to be like?

A

Soft, weak metals with low boiling points but very reactive with water and oxygen.

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8
Q

Why don’t metals in elemental form in groups 1 and 2 have many uses?

A

They are too reactive.

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9
Q

What compounds are common and useful?

A

S block compounds.

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10
Q

What is similar within groups in the periodic table?

A

Electron arrangements in their atoms.

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11
Q

What is the cause of differences between groups in the periodic table?

A

The size of the atom, it increases down the group.

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12
Q

What happens if sufficient energy is given to an atom (in group 1 and 2)?

A

An electron is lost and the atom becomes a positive ion.

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13
Q

What is needed to remove electrons and why?

A

Energy, because the electrons are attracted to the nucleus.

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14
Q

What is the first ionisation enthalpy of an element?

A

The energy needed to remove one electron from every atom in one mole of isolated gaseous atoms forming one mole of gaseous ions.

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15
Q

What is the general equation for first ionisation enthalpy?

A

X(g)-X^+(g)+e^-

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16
Q

What is the first ionisation enthalpy equation for oxygen?

A

O(g)-0^+(g)+e^-

17
Q

What is the first ionisation enthalpy for oxygen?

A

+1320 kJ/mol

18
Q

What electron does the first ionisation enthalpy remove and why?

A

One of the outer shell electrons, they are the most loosely held.

19
Q

What do group 0 have?

A

High first ionisation enthalpies.

20
Q

What does it mean if groups have a high first ionisation enthalpy?

A

They are hard to ionise.

21
Q

Why are group 0 elements hard to ionise?

A

They have full outer shells.

22
Q

What does it mean if groups have a low first ionisation enthalpy?

A

They are easy to ionise.

23
Q

What do group 1 have?

A

A low first ionisation enthalpy.

24
Q

Why are group 1 elements easy to ionise?

A

They have one electron in their outer shell.

25
Q

What are the peaks and troughs in a first ionisation enthalpy graph and why?

A

Peaks are group 0 as they are hard to ionise and troughs are group 1 as they are easily ionised.

26
Q

What is the electron shield theory?

A

Electron shielding from the nucleus increases as the number of shells increase, so less energy is needed to remove an outer shell electron.

27
Q

Why does it become harder to remove an outer shell electron as you go across the period?

A

The number of protons increases so nuclear charge increases.

28
Q

What causes variation of first ionisation enthalpy across periods?

A

The different energies and paired repulsions in sub-shells.

29
Q

What happens to the first ionisation enthalpies as you go down a group and why?

A

They decrease as the attraction between the nucleus and outer electrons decreases.

30
Q

What do group 1 and 2 metals first ionisation enthalpy correspond to?

A

It’s reactivity.

31
Q

What factors effect ionisation energy?

A

The size of the nuclear charge, the distance of the outer electrons to the nucleus, and the shielding effect on inner electrons.

32
Q

Why is it easier to remove an electron from a p-subshell than a s-subshell?

A

The p-subshell is further away from the nucleus and the s-subshell is shielding the electron so there is less attraction.

33
Q

Why is it easier to remove an electron from group 6 than group 5?

A

The p orbital starts to double fill in group 6 so there is a repulsion making it easier to remove the electron.

34
Q

What are the second, third, fourth and so on ionisation enthalpies?

A

The energy required to remove further electrons.

35
Q

What is the general equation for second ionisation enthalpy?

A

X^+(g)-X^2+(g)+e^-