EQUATIONS Flashcards

(91 cards)

1
Q

Circuits

RESISTANCE

(of a material used as a resistor in a circuit)

UNITS=?

A

R=ρL/A

UNITS: Ω (Ohms)

  • ρ=resistivity of the material
  • L=length of material
  • A=cross-sectional area
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2
Q

INTENSITY of a wave

A

=waves/m2

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3
Q

VELOCITY of a wave

A

V=λf

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4
Q

VOLTAGE in a circuit (3)

A

V=PE/q

V=Ed

V=Kq/r

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5
Q

KINETIC ENERGY

A

KE=½mv2

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6
Q

HARMONICS

FOR:

  1. String or pipe with MATCHING ends–
    • both nodes or antinodes
  2. String or pipe open at ONE end –
    • with one node and one antinode

λ=?

A

λ = 2L/n

λ = 4L/n

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7
Q

Snell’s Law

A

n1sinθ1 = n2sinθ2

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8
Q

Young’s Double Slit Experiment

A

x = λL/d

  • x is the distance between fringes
  • λ is the wavelength of light used
  • d is the distance between the two slits
  • L is the distance between the “double slit” and the final screen
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9
Q

TORQUE (3)

A

T=Fl

T=mgl

T=Frsinθ

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10
Q

GRAVITATIONAL PE

IN SPACE

A

PEgrav= - Gmm/r

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11
Q

PEELASTIC

A

PEelastic=½kx2

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12
Q

PEELECTRICAL (3)

A

PEelec=Kqq/r

PEelec=qEd

PEelec=qV

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13
Q

POTENTIAL ENERGY STORED IN A CAPACITOR (3)

A

PEcapacitor=½QV

PEcapacitor=½CV2

PEcapacitor=½Q2/C

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14
Q

MECHANICAL ENERGY (ME)

A

ME=KE+PE

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15
Q

WORK (2)

A

W=Δ ENERGY

W=Fdcosθ

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16
Q

RAMPS

A

Fm=mg (h/d)

  • h is the height of the ramp
  • d is the distance along its hypotenuse
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17
Q

LEVERS

A

Fm=mg( L1 / L2 )

  • L1 is the lever arm for the mass
  • L2 is the lever arm for the applied force
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18
Q

PULLEYS

A

Fm= mg / ( # of vertical ropes directly lifting the mass)

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19
Q

POWER (4)

A

P=ΔE/t

P=W/t

P=Fdcosθ

P=Fvcosθ

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20
Q

HYDRAULIC LIFTS (2)

A

Fm=mg (h1/h2)

Fm=mg (A1/A2)

h1=distance traveled by the large plunger

h2=distance traveled by the small plunger

A1 =cross-sectional area of the small plunger

A2 cross-sectional area of the large plunger

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21
Q

FORCE FOR A CONSTANT ELEC. FIELD

A

F=qE

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22
Q

FORCE FOR A POINT CHARGE ELEC. FIELD

A

F=Kqq/r2

<span>(Coulomb’s Law)</span>

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23
Q

STRENGTH OF FIELD (“E”) FOR A CONSTANT ELEC. FIELD (2)

A

E=F/q

E=V/d

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24
Q

STRENGTH OF FIELD (“E”) FOR A POINT CHARGE ELEC. FIELD

A

E=Kq/r2

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25
**ELEC. POTENTIAL ENERGY FOR A CONSTANT ELEC. FIELD**
**PEelec=qEd**
26
**ELEC. POTENTIAL ENERGY FOR A POINT CHARGE ELEC. FIELD**
**PEelec= (+/-) Kqq/r**
27
**VOLTAGE FOR A CONSTANT ELEC. FIELD**
**V=Ed**
28
**VOLTAGE FOR A POINT CHARGE ELEC. FIELD**
**V=Kq/r**
29
**Fmagnetic EXERTED ON A CHARGED PARTICLE,q, MOVING IN A MAGNETIC FIELD,B**
**F=qvBsinθ**
30
**CURRENT**
**I=Δq/Δt**
31
**OHM'S LAW**
**V=IR**
32
**ELECTRICAL POWER (3)**
**P=IV** **P=I2R** **P=V2/R**
33
**VELOCITY OF A WAVE**
**V=λf**
34
**THE BEAT FREQUENCY**
**fbeat= |f1 - f2|**
35
**THE DOPPLER EFFECT (2)**
**Δf/fsource= v/c** **Δλ/λsource= v/c**
36
**HARMONICS FOR A STRING OR PIPE WITH MATCHING ENDS--BOTH NODES OR BOTH ANTINODES**
**L= nλ/2** ## Footnote **or λ=2L/n**
37
**HARMONICS FOR A PIPE OPEN AT ONE END ONLY--ONE NODE AND ONE ANTINODE**
**L=nλ/4** ## Footnote **OR λ=4L/n**
38
**ENERGY OF A PHOTON**
**E=hf**
39
**INDEX OF REFRACTION, "n"**
**n=c/v**
40
**FOCAL POINT** **FOR MIRRORS ONLY**
**f=½r**
41
**THIN LENS EQUATION**
**1/p + 1/q = 1/f**
42
**MAGNIFICATION**
**M= -q/p**
43
**OPTICAL POWER**
**P= 1/f**
44
**TWO LENS SYSTEMS:** **MAGNIFICATION**
**M=m1m2**
45
**TWO LENS SYSTEMS:** **POWER**
**P=p1+p2**
46
**FRICTION (2)**
**Fkkmgcosθ** **Fssmgcosθ**
47
**THE CHARGE OF AN ELECTRON=** **(in Coulombs)**
**-1.6 x 10-19C**
48
**THE IDEAL GAS LAW**
**PV=nRT**
49
**THE FUNDAMENTAL THERMODYNAMIC RELATION**
**ΔG=ΔH-TΔS**
50
**EQUATION RELATING KEQ TO GIBBS FREE ENERGY (2 VARIATIONS)** **SPONTANEOUS IF ΔG IS (+/-)?**
**ΔG= -RTlnKeq** **OR** **Keq=e-ΔG/RT** **_SPONTANEOUS IF ΔG IS NEGATIVE_** **("EXERGONIC")**
51
**HEAT CAPACITY**
**c =ΔQ/ΔT**
52
**SPECIFIC HEAT**
**q=McΔT**
53
**FREEZING POINT DEPRESSION**
The freezing point of a liquid is depressed when a non-volatile solute is added according to: **∆T = kfmi** kf is a constant
54
**RAOULT'S LAW** **Vapor Pressure w/ a Non-Volatile Solute =**
Vapor Pressure w/ a Non-Volatile Solute = (mole fraction of the pure solvent, X)\*(Vp of the pure solvent, Vp°) **Vp = XVp°** **x=mole fraction of pure solvent** **Vp=Vapor pressure of pure solvent**
55
**RAOULT'S LAW** **TOTAL Vapor Pressure w/ a Volatile Solute =**
**Vptotal** **= Vpsolvent + Vpsolute** **( Xsolvent Vp°solvent) + (Xsolute Vp°solute)** (**mole fraction, X,** of sol**_vent_**\* **Vp°** of the sol**_vent_**) + (**mole fractio**n of the sol**_ute_**\* **Vp**° of the sol**_ute_**)
56
**OSMOTIC PRESSURE, Π**
**Π= iMRT** ## Footnote i = # of ions formed in solution M is the solute molarity R is the gas constant T is the absolute temperature
57
**BOILING POINT ELEVATION**
**∆T = kbmi** ## Footnote * where kb is a constant, * m is **MOLALITY** (**NOT** molarity) * i is the number of ions formed per molecule
58
**NERNST EQUATION**
**Ecell = E° - (.06/n) \* log ([lower]/[higher])** n=# moles of electrons transferred **Fe3+(aq)→Fe(s)** **=3 e's transferred**
59
**GIBBS FREE ENERGY**
**ΔG=ΔH-TΔS**
60
**GIBBS FREE ENERGY #3** _in association with:_ **Free energy and Cell potentials** (+/-) ∆G = SPONTANEOUS/ FAVORABLE?
**∆G = -nFE** n is the number of moles of electrons transferred F is Faraday’s constant E is the emf of the cell **NEGATIVE** ∆G = SPONTANEOUS/ FAVORABLE? ^^OR A **POSITIVE** E°**^^**
61
**GIBBS FREE ENERGY #2** _in association with:_ **Free energy and Equilibrium Constants** (+/-) ∆G = SPONTANEOUS/ FAVORABLE?
**∆G = - RTlnKeq** ## Footnote ∆G = free energy at any moment ∆G° = standard-state free energy R = ideal gas constant = 8.314 J/mol-K T = temperature (Kelvin) lnQ = natural log of the reaction quotient (+/-) ∆G = SPONTANEOUS/ FAVORABLE? **DEPENDS ON VALUE OF Keq** _SPONTANEOUS_: ∆G \< 0 K \> 1 _NON-SPONTANEOUS:_ ∆G \> 0 K \< 1
62
**GIBBS FREE ENERGY #1** _in association with:_ **TEMPERATURE and Free Energy** (+/-) ∆G = SPONTANEOUS/ FAVORABLE?
**∆G =∆H -T∆S** **NEGATIVE** ∆G= SPONTANEOUS / FAVORABLE
63
# Gases **DALTON'S LAW OF PARTIAL PRESSURES**
**Ptotal=P1+P2+P3...**
64
# Gases **GRAHAM'S LAW** **(EFFUSION & DIFFUSION)**
**E1/E2=√MW2/√MW1**
65
# Density & Specific Gravity **DENSITY, ρ**
**ρ=m/v**
66
# Give Units--No equation here **DENSITY OF WATER=?** **(2)**
**1000 kg/m3 OR 1.0 g/cm3** _REMEMBER_: **1 cm3 = 1mL** **1 L H2O=1 kg** **1 mL H2O=1 g**
67
**SPECIFIC GRAVITY** _FOR OBJECTS FLOATING IN LIQUIDS:_ *WHAT IS SIGNIFICANCE OF THE **FRACTION** OF THE OBJECT THAT **IS** SUBMERGED IN WATER?*
**SG= ρsubstancewater** ## Footnote ρ=density, m/v ρwater=1 g cm3 or 1000 kg/m3 *FOR OBJECTS FLOATING IN WATER:* ***FRACTION OF OBJECT SUBMERGED IS EQUAL TO THE SPECIFIC GRAVITY!***
68
**BUOYANT FORCE, Fbuoyant**
**Fbuoyant=ρvg**
69
# Fluid Pressure **_GENERAL_ PRESSURE FORMULA**
**P=F/A**
70
# Fluid Pressure **FLUID PRESSURE**
**P=ρgh**
71
# Fluid Flow **FLOW RATE**
**Q=AV** ## Footnote A=total cross-sectional area
72
# Fluid in motion **BERNOULLI'S EQUATION**
**K=P+ρgh+½ρv2** ## Footnote * **P**=random vibrational energy of the fluid molecules * **ρgh**= PEgravitational per volume of the fluid * **h**=height (**NOT** depth) * **½ρv2** = KE per volume of moving fluid molecules
73
# Energy Levels **WORK FUNCTION, φ**
**KE=E-φ**
74
# Energy Levels **ENERGY OF A PHOTON, "E"**
**E=hf**
75
# Chemistry **PERCENT % MASS**
**% MASS=** **Mass of ONE element/TOTAL mass of cpd** **x 100%**
76
# Equilibrium **LAW OF MASS ACTION** **Keq=?**
**Keq=** **[products]X / [reactants]Y**
77
# Le Chatelier's Principle **Qeq** ## Footnote **MORE\_\_\_ THAN \_\_\_** **RXN PROCEEDS TO THE \_\_\_**
**MORE REACTANT THAN PRODUCT** **RXN PROCEEDS TO THE RIGHT**
78
# Le Chatelier's Principle **Q\>Keq** ## Footnote **MORE\_\_\_ THAN \_\_\_** **RXN PROCEEDS TO THE \_\_\_**
**MORE PRODUCT THAN REACTANT** **RXN PROCEEDS TO THE LEFT**
79
# Evolution & Populations **HARDY-WEINBERG EQUILIBRIUM (2)**
**p2+2pq+q2=1** **p+q=1** ***p** is the frequency of the **"A"** allele in the population* ***q** is the frequency of the **"a"** allele in the population* ***p2** represents the frequency of the **homo**zygous genotype **AA*** ***q2** represents the frequency of the **homo**zygous genotype **aa*** ***2pq** represents the frequency of the **hetero**zygous genotype **Aa***
80
# Ochem **"FORMAL CHARGE"**
**FORMAL CHARGE=** **VALENCE - ASSIGNED**
81
**HÜCKEL'S RULE**
**4n + 2π** ## Footnote *To exhibit aromaticity, a ring system must have **exactly** 4n + 2π electrons*
82
# Circuits **CAPACITANCE**
**C= Q/V**
83
# Waves-The dB System **INTENSITY IN dB**
**=10\*log (I/Io)** ## Footnote **I***=intensity of wave (in W/m2)* **Io***=threshold of human hearing (given)*
84
# Chromatography **PAPER OR THIN LAYER CHROMATOGRAPHY (TLC)** **Rf=?**
**Rf=** DIST. TRAVELED BY **COMPONENT /**DIST. TRAVELED BY **SOLVENT**
85
**MICHAELIS-MENTEN EQUATION**
**Vo= Vmax [S] / Km+[S]**
86
**MICHAELIS CONSTANT, Km** **Km IS A MEASURE OF...?**
**Km=[S] at ½Vmax** ## Footnote **Km**= *MEASURE OF AN **ENZYME'S** AFFINITY FOR ITS **SUBSTRATE***
87
# Types of Enzyme Inhibition **LINEWEAVER-BURKE PLOTS** **Y-INTERCEPT=?**
**1/Vmax**
88
# Types of Enzyme Inhibition **LINEWEAVER-BURKE PLOTS** **X-INTERCEPT=?**
**-1/Km**
89
# Types of Enzyme Inhibition **LINEWEAVER-BURKE PLOTS** **SLOPE=?**
**Km/Vmax**
90
# Circuits **CAPACIT**_ANCE_**** ## Footnote *(_NOT_ PEcapacitor !)* How do Capacit**_ance_** and PEcapacitor relate?
**C=Q/V** ## Footnote Once solving for C, plug ***that*** into one of the 3 PEcapacitor formulas: **=½QV** **=½CV2** OR **=½Q2/C**
91
# Circuits **CAPACITANCE** ## Footnote wrt **AREA OF OVERLAP, A** b/t plates and **DISTANCE, D** b/t plates
**C=εA/d** ## Footnote * C is the capacitance (Farads) * A is the area of **overlap** of the two plates (m2) * ε is the **dialectric constant** of the material between the plates * for a vacuum, εr = 1 * d is the separation **between** the plates (m)