Extraction and use of metals Flashcards

1
Q

the more reactive a metal is…

A

the harder it is to extract it from a compound

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2
Q

lots of common metals react with…to form…

A

oxygen…oxides

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3
Q

what is the reaction that involves the separation of a metal from the oxygen?

A

a reduction reaction

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4
Q

what is the reducing agent?

A

the substance that reduces the metal

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5
Q

what is the most common reducing agent?

A

carbon

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6
Q

copper oxide is reduced to copper:

A

2CuO + C = 2Cu + CO2

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7
Q

Methods of extraction are linked to the…

A

order of reactivity

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8
Q

only metals…than…can be reduced by…

A

less reactive…carbon…carbon

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9
Q

very reactive metals form…

A

very stable ores

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10
Q

metals that are more reactive than carbon need to be extracted using…

A

electrolysis

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11
Q

what is the melting point of aluminium?

A

2000 degrees celcius

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12
Q

what is aluminium dissolved in?

A

molten cryolite (a less common ore than aluminium)

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13
Q

What does the molten cryolite do?

A

it brings the temperature down to about 900 degrees celcius

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14
Q

what electrode are the aluminium ions attracted to?

A

the negative

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15
Q

what happens to the aluminium atoms once they gain electrons?

A

they sink to the bottom

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16
Q

why do the positive electrodes always need to be replaced?

A

they get worn down by reacting with oxygen

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17
Q

at the negative electrode:

A

Al3+ + 3e- –> Al

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18
Q

at the positive electrode:

A

202- –> O2 + 4e-

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19
Q

why is electrolysis expensive?

A
  • it uses lots of electricity
  • the need to heat the electrolyte
  • the frequent replacement of electrodes
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20
Q

what are the raw materials used for extracting iron from iron ore?

A
  • iron ore
  • coke
  • limestone
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21
Q

what is coke?

A

almost pure carbon

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22
Q

what is the purpose of limestone?

A

to take away impurities in the form of slag

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23
Q

step 1:

A

hot air is blasted into the furnace, making the coke burn much faster than normal
this raises the temperature to about 1500 degrees Celsius

24
Q

Step 2:

A

the coke burns to produce carbon dioxide

25
step 2 equation:
C + O2 --> CO2
26
step 3:
the carbon dioxide then reacts with the unburnt coke to form carbon monoxide
27
step 3 equation:
CO2 + C --> 2CO
28
Step 4:
the carbon monoxide then reduces the iron ore to iron
29
step 4 equation:
3CO + Fe2O3 --> 3CO2 + 2Fe
30
step 5:
the iron is molten at this temperature but is also very dense, so it runs straight to the bottom of the furnace where it's tapped off
31
What is the main impurity from this process?
sand (silicon dioxide)
32
what removes the impurity?
the limestone
33
Step 1 of removing the impurity:
the limestone is decomposed by the heat into calcium oxide and carbon dioxide
34
Step 1 of removing the impurity: equation
CaCO3 --> CaO + CO2
35
Step 2 of removing the impurity:
the calcium oxide reacts with the sand to form calcium silicate, or slag, which is molten and can be tapped off
36
What is the cooled slag used for?
- road building | - fertiliser
37
what are the properties of aluminium and iron? (6)
- both dense and lustrous (shiny) - high melting points - high tensile strength - malleable - good conductors of electricity - good conductors of heat energy
38
uses of iron:
- wrought iron (malleable) | - alloys
39
what is cast iron made of?
iron, carbon and silicon
40
what is steel made of?
iron, carbon and usually some other metals
41
what is the main problem with iron?
it corrodes easily
42
uses of aluminium:
- it doesnt corrode so is used for products that come into contact with water (eg drinks cans) - aluminium is much less dense than iron so can be used for bicycle frames and aeroplanes
43
What is ammonia used for?
Fertilisers Making nitric acid Making nylon
44
Where does the nitrogen come from?
Air
45
Where does the hydrogen come from?
Natural gas
46
What temperature does the Haber process happen at?
450
47
What pressure does the haber process happen at?
200 atm
48
What is the catalyst used for the Haber process?
Iron
49
First step contact process
Majing sulfur dioxide
50
Second step contact process
Making sulfur trioxide
51
Third step contact process
Making liquid oleum
52
Fourth step contact process
Making concentrated sulfuric acid
53
Uses for sulfuric acid
Fertilisers Detergents Paints
54
Temperature contact process
450
55
Pressure contact process
2 atm
56
Catalyst contact process
Vanadium(v) oxide