IQR 3 Flashcards

(23 cards)

1
Q

Atomic radius: Left to right across a period

A

Moving left to right across a period the atomic radius decreases: The number of protons increase, causing a stronger pull in the outer electron towards the nucleus resulting in a smaller radius.

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2
Q

Atomic radius: Moving down a group

A

The atomic radius increases. More shells create screening effect as the increased shells block force of attraction towards nucleus resulting in larger radius.

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3
Q

Ionisation energy definition

A

Amount of energy required to remove the most loosely bound electron from an atom or ion in the gaseous state.

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4
Q

Ionisation energy: Moving from left to right

A

Ionisation energy increases: With a smaller atomic radius (Number of shells remain but increased number of protons). Causes stronger force of attraction, hence more energy is required to remove the valence electron.

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5
Q

Moving down a group

A

Ionisation energy decreases: Although number of protons increases the number of shells also increases. Therefore, less energy is required to remove it.

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6
Q

Factors affecting the magnitude of ionisation energy:

A

Nuclear charge: The higher the charge the higher the energy
Shielding effect: more shells= less energy.
Radius: More distance between nucleus and outer electrons= reduced ionisation energy.
Sublevel: Electron from full or half sublevels requires more energy.

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7
Q

Relationship between atomic radius and ionisation energy

A

Inversely proportional

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8
Q

MP/BP: going down groups 1,2,13, 14

A

Decreases: As atoms get bigger the nuclei get further away from the outside electron. The attraction falls and the metallic bonds weakens. hence, atoms are more easily pulled apart.

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9
Q

MP/BP going down groups: 15, 16, 17, 18

A

Attraction between molecules called van der waals dispersion forces. As molecules get bigger dispersion forces gets bigger so there melting and boiling forces rise.

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10
Q

Two elements liquid at room temperature

A

Mercury and Bromine

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11
Q

Electronegativity: Left to right

A

Increases: Atomic radius decreases, ability of nucleus to attract increases.

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12
Q

Electronegativity: Top to bottom

A

Decreases: More shells causes the shield effect. Which means it can’t pull electrons as well

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13
Q

Electronegativity and ionisation energy relationship

A

Directly proportional

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14
Q

Metallic character: Left to right

A

Decreases: As there is decreasing atomic radius, the valence electron become more closely bound to the nucleus resulting in decreasing electrical and thermal conductivities.

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15
Q

Metallic character: Top to bottom

A

Metallic character increases. As atomic radius increases the valence electron become more loosely bound and thus more electrical and thermal conductivity.

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16
Q

Reactivity with water

A

metals may react with water to produce hydrogen gas and metal

17
Q

Reactivity with water trend group 1

A

Atomic radius increases and number of shells, meaning less ionisaton energy. The electron is more easily able to be get rid of and thus reactivity increases.

18
Q

Reactivity with water group 2

A

Group 2 elements react at varying temperatures, in comparison to group 1 the atomic radius is less so reactivity decreases.

19
Q

Reactivity in general from left to right

A

Reactive metal (Incomplete valence shell to unreactive noble gas (Full valence shell

20
Q

Reactivity in general down groups 1 and 2

A

Electronegativity energy decreases and radius incerases so high reactivity as going down.

21
Q

Reactivity in general going down groups 5

A

15-17
Non metals. More attarctive and lower radius poorer tendency to gain electrons.

22
Q

Periodicity

A

Regular recurrence of events or properties