IQR 3 Flashcards
(23 cards)
Atomic radius: Left to right across a period
Moving left to right across a period the atomic radius decreases: The number of protons increase, causing a stronger pull in the outer electron towards the nucleus resulting in a smaller radius.
Atomic radius: Moving down a group
The atomic radius increases. More shells create screening effect as the increased shells block force of attraction towards nucleus resulting in larger radius.
Ionisation energy definition
Amount of energy required to remove the most loosely bound electron from an atom or ion in the gaseous state.
Ionisation energy: Moving from left to right
Ionisation energy increases: With a smaller atomic radius (Number of shells remain but increased number of protons). Causes stronger force of attraction, hence more energy is required to remove the valence electron.
Moving down a group
Ionisation energy decreases: Although number of protons increases the number of shells also increases. Therefore, less energy is required to remove it.
Factors affecting the magnitude of ionisation energy:
Nuclear charge: The higher the charge the higher the energy
Shielding effect: more shells= less energy.
Radius: More distance between nucleus and outer electrons= reduced ionisation energy.
Sublevel: Electron from full or half sublevels requires more energy.
Relationship between atomic radius and ionisation energy
Inversely proportional
MP/BP: going down groups 1,2,13, 14
Decreases: As atoms get bigger the nuclei get further away from the outside electron. The attraction falls and the metallic bonds weakens. hence, atoms are more easily pulled apart.
MP/BP going down groups: 15, 16, 17, 18
Attraction between molecules called van der waals dispersion forces. As molecules get bigger dispersion forces gets bigger so there melting and boiling forces rise.
Two elements liquid at room temperature
Mercury and Bromine
Electronegativity: Left to right
Increases: Atomic radius decreases, ability of nucleus to attract increases.
Electronegativity: Top to bottom
Decreases: More shells causes the shield effect. Which means it can’t pull electrons as well
Electronegativity and ionisation energy relationship
Directly proportional
Metallic character: Left to right
Decreases: As there is decreasing atomic radius, the valence electron become more closely bound to the nucleus resulting in decreasing electrical and thermal conductivities.
Metallic character: Top to bottom
Metallic character increases. As atomic radius increases the valence electron become more loosely bound and thus more electrical and thermal conductivity.
Reactivity with water
metals may react with water to produce hydrogen gas and metal
Reactivity with water trend group 1
Atomic radius increases and number of shells, meaning less ionisaton energy. The electron is more easily able to be get rid of and thus reactivity increases.
Reactivity with water group 2
Group 2 elements react at varying temperatures, in comparison to group 1 the atomic radius is less so reactivity decreases.
Reactivity in general from left to right
Reactive metal (Incomplete valence shell to unreactive noble gas (Full valence shell
Reactivity in general down groups 1 and 2
Electronegativity energy decreases and radius incerases so high reactivity as going down.
Reactivity in general going down groups 5
15-17
Non metals. More attarctive and lower radius poorer tendency to gain electrons.
Periodicity
Regular recurrence of events or properties