Lesson 1: The Nature And Structure Of Organic Molecules Flashcards

1
Q

Two most important persons to recognize that carbon (C) is tetravalent.

A

German chemist Kekule and Scottish chemist Couper

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2
Q

This means that carbon can formm four covalent bonds with other atoms such as hydrogen (H), oxygen (O) and nitrogen (N).

A

Tetravalent

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3
Q

________ having four valence electrons cannot bond easily with other atoms like that of carbon.

A

Silicon

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4
Q

In the nature of carbon, it can form a ______, _______ and _________ with a wide array of organic substances.

A

Linear, branched and cyclic bonds

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5
Q

Carbon can form a more _______________ if the carbon atom will have single, double and triple bonds.

A

Diverse molecular structure

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6
Q

Who notion about the chemical inertness of the noble gases indicated a high degree of stability of the electron configuration of these elements.

A

Gilbert N. Lewis

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7
Q

It is a very simplified representation of the valence shell electrons in a molecule.

A

Lewis structure

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8
Q

_____________ of a molecule happens when it acquire the complete (octet) eight electrons in the outer most shell of an atom.

A

Chemical bonding

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9
Q

An atom becomes _____________ when it loses an electron.

A

Negatively charged (–)

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10
Q

An atom becomes ______________ when it gains an electron.

A

Positively charged (+)

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11
Q

Bond formed between atoms

A

Ionic bond

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12
Q

When the two atoms shared their electrons it forms ___________.

A

Covalent bond

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13
Q

The covalent bond can be polar if the electrons shared are ___________.

A

Not equal

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14
Q

The covalent bond can be non polar if the electrons shared are __________.

A

Equal

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15
Q

Classification of organic compounds

A

Hydrocarbons
Heterocatoms

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16
Q

Organic compounds containing hydrogen and carbon.

A

Hydrocarbons

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17
Q

Hydrocarbons are also classified into two, these are___________ and _________ composed of double or triple bonds.

A

Saturated and unsaturated

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18
Q

Elements aside from carbon and hydrogen which is incorporated in organic compounds are called…..

A

Heteroatoms

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19
Q

Most common heteroatoms

A

Oxygen, nitrogen and the halogens.

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20
Q

Hydrocarbons, which contain only carbon and hydrogen are two types-the _______ and the _________.

A

Aliphatics and aromatics

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21
Q

Belongs to the aliphatics are

A

Alkanes
Alkenes
Alkynes; and
Their cyclic analogs

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22
Q

Heteroatoms with halogens are

A

Organic halides
Alkyl and aryl halides

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23
Q

Heteroatoms with oxygen

A

Alcohols
Phenols
Ethers
Aldehydes
Ketones
Carboxylic acids
Anhydrides
Esters

24
Q

Heteroatoms with nitrogen are

A

Amines
Amides
Amino acids

25
Heteroatoms with sulfur are
Thiols Sulfides
26
Greenhouse gas _________ is made up of hydrocarbons.
Methane
27
Some applications of organic compounds that we encounter everyday.
Methane Fuel Vinegar Wine
28
Types of organic molecules' reactions
Addition reaction Substitution reaction Elimination reaction Rearrangement reaction
29
Another category, ________ and _________ may fall naturally into one of the four types of organic reactions.
Oxidation and reduction reaction
30
Used in chemical reaction consists of a substrate and reagent.
Reactants
31
Reactants are transformed into ________ under the proper reaction conditions.
Products
32
It is the reactant that is acted upon or attacked by the reagent; it is the molecule which contains the carbon atoms to which bonds are broken and made.
Substrate
33
The organic reactions such addition, elimination, substitution and rearrangement is based on the........
Changes that occur in bonding to carbon atoms in the substrate
34
It is a reaction that can be identified if there is an increase in the number of atoms or groups attached to a carbon(s) in the substrate.
Addition reaction
35
In the addition reaction, each carbon atom in the unsaturated (double bond) substrate gets more atom resulting in a ____________.
Saturated product
36
In ______________, an atom or a group of atoms is removed from the substrate, thus there's is a decrease in the number of atoms or groups attached to carbon.
Elimination reaction
37
In elimination reaction, the substrate is transformed to a more _____________.
Unsaturated (single bond) product
38
It is a reaction that characterized by the replacement of a functional group in a molecule or ion by another functional groups.
Substitution reaction
39
A ________________ is a broad class of organic reactions where the carbon skeleton of a molecule is rearranged to hive a structural isomers of the original molecule.
Rearrangement reaction
40
The most common type of reaction which is also found in the organic reactions are the __________ and __________.
Oxidation Reduction reaction
41
Oxidation and reduction reaction are defined according to the increase or decrease in ________ or ________ content.
Oxygen Hydrogen
42
A reaction that occurs when there is an increase in the oxygen content and/or a decrease in the hydrogen content of the substrate.
Oxidation reaction
43
It is a reaction where there is an increase hydrogen content and/or a decrease in the oxygen content of the substrate.
Reduction reaction
44
The _____________ is the step by step events by which a substrate is converted to products at a given set of conditions.
Reaction mechanism
45
The order and breaking of bond are described including the bonds that is formed its relative rate by the action of the ___________.
Catalyst
46
Formed in one step and then consumed in a later step of the reaction mechanism.
Reaction intermediates
47
The slowest step in the mechanism is called the ___________ or __________.
Rate determining Rate-limiting step
48
_________ are formed from the transformation of reactants and reagents.
Products
49
When the covalent bond breaks, it can form either ________ or ________ cleavage when bond to carbon atom.
Homolytic Heterolytic
50
For a __________ to carbon it can form carbon radical.
Homolytic bond
51
It can be trivalent carbon anion, or carbanions or can be carbon cation or carbocations.
Heterolytic bond
52
Reactants are classified into two, the substrate and reagents. The reagents have three types, what are these?
Nucleophilic Electrophilic Radical-like
53
You should know the three types of reagents so that you will be able to identify type of __________ that will occur in a reaction.
Bond cleavage
54
A reagent who loves electrons, they are consist of pairs of electrons that can be used for bond formation. They attack positively charged atoms or low electron density.
Nucleophilic reagents (nucleus loving) or nucleophiles
55
It is a type of reagent that are electron deficient, capable of forming new bonds by accepting a pair of electrons, they attack negatively charged electrons or high electron density.
Electrophilic reagents (electron loving) or electrophiles
56
This reagent have odd number of electrons which react easily and attack high electron density atoms.
Radical-like reagent