LIPIDS Flashcards

(58 cards)

1
Q

Fixed Oils, Fats, Waxes and Fatty Acids

A

LIPIDS

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2
Q

Are esters of long-chain fatty acids and alcohols or of closely related derivatives.

A

LIPIDS

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3
Q

Are soluble in non-polar organic solvents and generally insoluble in water.

A

LIPDS

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4
Q

Uses of Lipids in Medical/Pharmaceutical

A

EMOLLIENT
VEHICLES FOR MEDICATIONS
THERAPEUTIC PROPERTY
ENTERAL AND PARENTERAL NUTRITION

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5
Q

Lipids Uses in Industries

A

SOAPS
PAINTS

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6
Q

2 type of Alcohol:

A

FIXED OILS AND FATS
WAXES

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7
Q

Glycerol combine with Fatty Acids

A

FIXED OILS AND FATS

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8
Q

High mol. wt. alcohol (Cetyl alcohol) combined with Fatty acids

A

WAXES

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9
Q

Primary function is for food (energy) storage

A

FIXED OILS AND FATS

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10
Q

Fixed oils and fats are obtained from either:

A

PLANTS: PEANUT OIL, OLIVE OIL
ANIMALS: LARD

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11
Q

Important products used pharmaceutically, industrially and as
food.

A

FIXED OILS AND FATS

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12
Q

May occur in various parts of the plants, but as a general rule in seeds.

A

VEGETABLE OILS AND FATS

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13
Q

may contain larger quantities and the usual sources of fixed oils

A

SEEDS

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14
Q

Examples of seeds:

A

CASTOR SEED
COTTON SEED
SESAME SEED
HEMP SEED
LINSEED
ALMOND SEED
COCONUT

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15
Q

Fixed Oils are sometimes classified as:

A

DRYING OILS
SEMI-DRYING OILS
NON-DRYING OILS

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16
Q

May also be of plant and animal origin

A

WAXES

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17
Q

Are liquid at normal temperature

A

FIXED OILS AND FATS

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18
Q

Are semi-solid to solid at ordinary temperature

A

WAXES

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19
Q

Solid vegetable oil

A

COCOA BUTTER

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20
Q

MOST ANIMAL FATS ARE SOLID

A

TRUE

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21
Q

(MOST VEGETABLE OILS ARE LIQUID AT ORDINARY TEMPERATURE)

A
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22
Q

Most Vegetable Oils are liquid at ordinary temperature except:

A

COCOA BUTTER - SOLID VEGETABLE OIL

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23
Q

Most Animal Fats are solid except

A

COD LIVER OIL - LIQUID ANIMAL FAT

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24
Q

Fixed Oils and Fats of Vegetative Origin are obtained by ______.

A

EXPERSSION IN HYDRAULIC PRESSES

25
Fixed Oils and Fats of Vegetative Origin are obtained by Expression in Hydraulic Presses:
COLD - VIRGIN/ COLD PRESSED OIL HOT - HOT PRESSED OIL SOMETIMES ORGANIC SOLVENTS ARE USED FOR THE EXTRACTION OF OILS
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are separated from other tissues by rendering with steam or without steam.
ANIMAL FATS
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Classification of Fixed Oils:
SATURATED MONOSATURATED POLYSATURATED
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Saturated Fixed Oils:
COCONUT OIL PALM OIL PALM KERNEL OIL
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Monosaturated Fixed Oils:
CASTOR OIL OLIVE OLIVE PEANUT OIL RAPESEED OIL
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Cacao Butter/Cocoa Butter
THEOBROMA OIL
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Hydrous Woolfat
LANOLIN
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Woolfat
ANHYDROUS LANOLIN
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Are esters resulting from the condensation of high molecular weight, straight-chain acids and alcohols.
WAXES
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FATS AND RELATED COMPOUNDS
THEOBROMA OIL- CACAO BUTTER/COCOA BUTTER LANOLIN- HYDROUS WOOLFAT ANHYDROUS WOOLFAT - WOOLFAT HYDROGENATED VEGETABLE OILS LARD
35
Polysaturated Fixed Oils:
ALMOND OIL CORN OIL COTTONSEED OIL COD LOVER OIL LINSEED OIL PERSIC OIL SOYBEAN OIL SESAME OIL SAFFLOWER OIL SUNFLOWER OIL
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CH3(CH2)14CO2-(CH2)15CH3
BEESWAX
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CH3(CH2)24CO2-(CH2)29CH3
CARNAUBA WAX
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CH3(CH2)30CO2-(CH2)33CH3
SPERMACETI
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General Uses of Waxes:
HARDENS OINTMENTS AND CREAMS PREPARATION OF CERATES PROTECTIVE COATING IN INDUSTRY AND ART
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WAXES PLANTS:
CARNAUBA WAX BAYBERRY WAX
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WAXES INSECTS:
BEESWAX LACWAX
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WAXES: OTHER ANIMAL:
SPERMACETI
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No C-C double bonds
SATURATED FATTY ACIDS
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The presence of double bonds in fatty acids significantly lowers the melting point relative to a saturated fatty acid.
SATURATED FATTY ACIDS
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______ acids of less than eight carbon atoms are liquid at physiological temperature, whereas those containing more than ten are solid.
SATURATED FATTY ACIDS
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No C-C double bonds
SATURATED FATTY ACIDS
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Example of Saturated Fatty Acid:
LAURIC ACID MYRISTIC ACID PALMITIC ACID STEARIC ACID ARACHIDIC ACID
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With double bonds
UNSATURATED FATTY ACIDS
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With double bonds
UNSATURATED FATTY ACIDS
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Oxygen saturates the double bonds to form oxides that may polymerize to form hard films (important in film industry)
UNSATURATED FATTY ACIDS
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Double bonds also take up hydrogen in the proper conditions producing semi-solid fats that are used extensively as cooking fats and shortening
UNSATURATED FATTY ACIDS
52
Fixed Oils are classified based on their ability to absorb oxygen from the air: Drying oils, Semi- drying oils, and Non-drying Oils
UNSATURATED FATTY ACIDS
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the number of mg of KOH required to saponify the esters contained in 1 g of the substance.
ESTER VALUE
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the number of mg of KOH required to neutralized the free acids and saponify the esters contained in 1 g of the substance is equal to the sum of Acid Value and Ester Value.
SAPONIFICATION VALUE
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the number of mg of KOH required to neutralize the free acids contained in 1 g of the substance
ACID VALUE/ ACID NUMBER
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the number of grams of Iodine absorbed, under prescribed conditions, by 100 g of the substance.
IODINE NUMBER
57
USP TESTS FOR FATTY ACIDS
ESTER VALUE SAPONIFICATION VALUE ACID VALUE / ACID NUMBER IODINE NUMBER USP TESTS
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Examples of Fixed Oils:
DRYING OILS NON-DRYING OILS