Midterm 2 Flashcards
(112 cards)
CEC
cation exchange capacity
number of exchangable cations which soil solids can adsorb (cmol/kg soil)
Exchangable cations
cations which are readily displaced, by mass ion effect, from begat colloids which adsorbed on
Kaolinite vs Montmorillonite CEC approx vales
k: 1-1, no shrink-swell, low SSA (3-15)
M: 2-1, shrink-swell, high SSA (~100)
approz FE, Al osides CEC
~3 (weathered tropical environ)
Examples of base cations
Ca2+, Mg2+, K+, Na+
Base saturation
Fraction of cations on the ction exchange sites occupied by base cations
Anion exchange capacity
AEC
Number of exchangale anions which soils can adsorb
AEC with high pH
negative charge created!
where salts accumulate
at top of soil wheninternal drainage is inadequite to drain
Electrical Conductivity
EC
capacity of substance to conduct electric current
Exchangable Sodium Percentage
ESP
identifies degree to which exchange complex is saturated with sodim
ESP formula
(Exchangable sodium/CEC) times 100
pH related to ESP
ESP <15=<8
>15=-7.5-8.5
>15=>8
LOL FIX
consequenses of salinity
hurt plant growth
reduce water quality
soil erosion
damage infastructure
SOM
soil organic matter
complex. resistant mixture of brown amorphous/ colloidal organic compounds from microbial decomp and synthesis
OM input
forest litter, roots, animal excretion, microbial biomass
physical props SOM
part dens= 900-1300kg/m^3 bul dens=180-200 f=~0.9m^3/m^3 therm props= all lower than mineral water retention higher than mineral
primary components of SOM
non-humic substances
from plant/animal residues
partially decomped
20-30%
Secondary components of SOM
humic subs from breaking down organic structures and synth new ones fulvic acids, humin, humic acids 60-80% Rather decomp resist
Fulvic Acids
Smallest and “simple”
Soluble in any pH
brown colour in H2O
Humic Acids
btw the two
many carboxyl groups to get acidic
reactive
Humin
High molecular weight
“complex”
slow break down (decades of 100s)
CEC and pH relation
CEC high at high pH and low at low pH
low pH with humic groups
carboxyl groups undissociated (total negative charge=low)
can approach each other and bond
flocculate at low pH