organic 1 Flashcards

1
Q

gas

A

domestic fuel

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2
Q

petrol

A

cars

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3
Q

kerosene

A

aircrafts

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4
Q

diesel

A

cars+lorries

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5
Q

sigma bond joins

A

carbon to 4 other atoms

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6
Q

sigma bond

A

overlap of 2 orbitals (which each contain one electron) the bond has 2 shared electrons one from each orbital

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7
Q

tetrahedral shape in alkanes

A

the repulsion of atoms around a carbon result in 3d tetrahedral arrangement

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8
Q

how does the sigma bond affect movement of atoms

A

allow atoms to rotate freely so they can make different shapes. Shapes are not rigid

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9
Q

how is boiling point of alkanes affected by chain length

A

bp increases with chain length as the sa increases and there are more surface points of contact resulting in Greater London forces

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10
Q

how is boiling point of alkanes affected by branches

A

branched isomers have lower bp
1. fewer surface point of contact between molecules and weaker London forces
2. the shape means the branches get in the way and prevent molecules form getting as close as when straight, weaker lld forces

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11
Q

incomplete combustion products

A

co/c and water

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12
Q

complete combustion products

A

co2 and water

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13
Q

bromination of methane initiation reaction

A

br-br=br+br

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14
Q

bromination of methane step 1 propagation

A

Br.+ch4=hBr+ch3.

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15
Q

bromination of methane step 2 propagation

A

Ch3.+Br2=Ch3Br+Br.

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16
Q

shape of alkene

A

trignal planar
120
3 regions of density around each carbon
3 regions repel each other

17
Q

stereoisomer

A

same structural formula but different arrangement of the atoms in space

18
Q

why are alkenes more reactive than alkanes

A

sigma and pi bonds
sigma bonds concentrated above and below plane of sigma so more exposed to electrons
pi bond breaks more readily

19
Q

heterolytic fission

A

covalent bond is broken shared pair of electrons taken by one of the atoms

20
Q

homiletic fission

A

one electron goes with each atom when covalent bond is split

21
Q

disposing polymers

A

unreative saturated back bone makes It de biodegradable

22
Q

pvc recycling

A

pvc is hazardous as high in chlorine
when burnt releases hydrogen chloride a corrosive gas

23
Q

feed stock recycling

A

reclaim monomers gases or oils from waste polymers
able to handle unsorted ad unwashed polymers