Organic Chem Flashcards

1
Q

Combustion

A

reaction of hydrocarbon with o2. Hydrocarbon + O2 => CO2 + H20 + energy. CO will form if combustion incomplete(limited o2)

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2
Q

Substitution reactions

A

Halogenation, Hydrolysis, Hydrogen Halide with alcohol

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3
Q

Addition reactions

A

Halogenation, Hydrogenation, Hydrohalogenation, Hydration

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4
Q

Elimination Reactions

A

Dehydration, Dehydrohalogenation, Cracking

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5
Q

Hydrogentation (Addition)

A

Hydrogen + Alkene/alkyne - alkane

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6
Q

Halogenation (Addition)

A

Halogen + alkene/alkyne - haloalkane

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7
Q

Hydrohalogenation (addition)

A

Hydrogen halide + alkene/alkyne - haloalkane (major and minor)

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8
Q

Hydration

A

water + alkene/alkyne - alcohol (major and minor)

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9
Q

Markovnikovs Rule (For addition reactions involving hydration and hydrohalegenation)

A

H atom attaches to C atom that already has the most H atoms to form major product

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10
Q

Zaitzevs rule(Dehydrohalogenation and Dehydration)

A

H atom removed from C atom that has least number of H atoms to form major product

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11
Q

dehydrohalogenation

A

haloalkane - NaX + alkene + water (Zaitzev) where x is a halogen. (If a different base is used it becomes BaseX)

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12
Q

Dehydration

A

alcohol - water + alkene (Zaitzev)

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13
Q

Cracking

A

alkane - alkane + alkene

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14
Q

Halogenation (Sub)

A

Alkane + halogen - haloalkane + hydrogen halide

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15
Q

Haloalkane hydrolysis (s)

A

haloalkane + H2O/NaOH/KOH - alcohol + HX/NaX/KX where X is the halogen

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16
Q

Hydrohalogenation of alcohols(S)

A

alcohol + hydrogen halide - haloalkane + water