Organic Mechanism's Flashcards

(33 cards)

1
Q

What is the mechanism from alkane to alkene
Conditions

A

Thermal Cracking - Elimination
High Temp + Pressure

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2
Q

What is the mechanism from alkene to alkane
Conditions

A

Electrophilic Addition
With H2
Ni catalyst
200 degrees

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3
Q

What is the mechanism from alkane to haloalkane
Conditions

A

Free Radical Substitution
UV light

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4
Q

What is the mechanism from alkene to haloalkane
Conditions

A

Electrophilic addition
With HX

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5
Q

What is the mechanism from haloalkane to alkene
Conditions

A

Elimination
Heat and ethanol NaOH

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6
Q

What is the mechanism from alkene to alcohol
Conditions

A

Electrophilic addition
Sulfuric acid and steam

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7
Q

What is the mechanism from alcohol to alkene

A

Elimination - Dehydration
Al2O3 and sulfuric acid

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8
Q

What is the mechanism from haloalkane to alcohol
Conditions

A

Nucleophilic substitution
NaOH in solution
warm

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9
Q

What is the mechanism from haloalkane to Nitrile

A

Nucleophilic substitution
Warm ethanoic KCN

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10
Q

What is the mechanism from haloalkane to amine

A

Nucleophilic substitution
2 NH3
hot and ethanoic

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11
Q

What is the mechanism from alcohol to carboxylic acid

A

Reflux
Acidified potassium dichromate
Primary alcohol

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12
Q

What is the mechanism from alcohol to aldehyde

A

Distillation
Primary alcohol
acidified potassium dichromate

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13
Q

What is the mechanism from aldehyde to carboxylic acid

A

Reflux
Potassium dichromate

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14
Q

What is the mechanism from aldehyde to alcohol

A

Reduction
NaBH4

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15
Q

What is the mechanism from alcohol to ketone

A

Oxidation
Acidified potassium dichromate
Secondary alcohol

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16
Q

What is the mechanism from ketone to alcohol

A

Reduction
NaBH4

17
Q

What is the mechanism from aldehyde to hydroxy nitrile

A

Nucleophilic addition
KCN

18
Q

What is the mechanism from ketone to hydroxy nitrile

A

Nucleophilic addition
KCN

19
Q

What is the mechanism for acyl chloride to carboxylic acid

A

nucleophilic addition elimination
Acylation (hydrolysis)
Water

20
Q

What is the mechanism for acyl chloride to ester

A

Nucleophilic addition elimination
Acylation
Alcohol

21
Q

What is the mechanism for acyl chloride to amide

A

Nucleophilic addition elimination
Acylation
2 ammonia

22
Q

What is the mechanism for acyl chloride to N-substituted amide

A

Nucleophilic addition elimination
Acylation
2 Primary amine

23
Q

What is the mechanism for benzene to nitrobenzene

A

Electrophilic substitution
Nitration
Concentrated nitric and sulphuric acid
50 degrees

24
Q

What is the mechanism for benzene to aromatic ketone

A

Electrophilic substitution
Friedel Crafts acylation
Acyl chloride/acid anhydride + AlCl3 cataylst

25
What is the mechanism from alkene to alkyl hydrogensulphate
Electrophilic substitution Concentrated sulphuric acid
26
What is the mechanism from alkyl hydrogensulphate to alcohol
Hot water
27
what is the mechanism from amine to amide
Acyl chloride/acid anhydride nucleophilic addition - elimination
28
What is the mechanism from ketone to 2-hydroxynitrile
Nucleophilic addition HCN
29
What is the mechanism from alcohol to ester
esterification Carboxylic acid Acyl chloride acid anhydride
30
What is the mechanism from nitrile to amine
Reduction H2 Ni 200 degrees
31
What is the mechanism from benzene to cyclohexene
H2 Ni Reduction
32
Whats the mechanism from aromatic ketone to aromatic alcohol
NaBH4 reduction
33
Whats the mechanism from Nitrobenzene to phenylamine
Sn HCl then NaOH Reduction