Organic Synthesis Reactions Flashcards by Jess Sails

Q

primary amine –> N-substituted amide

A

acyl chloride

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Q

bromoalkane –> primary amine

A

NH3
reflux

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Q

alkane –> bromoalkane

A

Br2
UV light

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Q

alkene –> alkane

A

Ni catalyst
150 degrees and pressure

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Q

alkene –> dibromoalkane

A

HBr
20 degrees

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Q

alkene –> dibromoalkane

A

HBr
20 degrees

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Q

secondary bromoalkane –> secoondary alcohol

A

NaOH
reflux

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Q

bromoalkane –> primary alcohol

A

NaOH
reflux

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Q

alkene –> primary alcohol

A

H3PO4 catalyst
steam
300 degrees

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Q

primary alcohol –> alkene

A

conc. H2SO4
170 degrees and pressure

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Q

secondary alcohol –> ketone

A

K2Cr2O7
H2SO4
reflux

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Q

primary alcohol –> aldehyde

A

K2Cr2O7
H2SO4
heat then distil

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Q

ketone –> cyanohydrin

A

HCN

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Q

aldehyde –> cyanohydrin

A

HCN

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Q

aldehyde –> carboxylic acid

A

K2Cr2O7
H2SO4
reflux

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Q

primary amide –> carboxylic acid

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A

H+ heat

Q

carboxylic acid –> ester

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A

alcohol
H+ catalyst
reflux

Q

ester –> carboxylic acid

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A

H+
reflux

Q

acyl chloride –> ester

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A

alcohol

Q

benzene –> nitrobenzene
(NITRIFICATION)

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A

H2SO4
HNO3
55 degrees

Q

sulfonation of benzene

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A

fuming H2SO4
40 degrees

Q

acylation of benzene

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A

RCOCl
AlCl3 catalyst
reflux

Q

alkylation of benzene

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A

RCl
AlCl3 catalyst
reflux

Q

benzene –> chlorobenzene
(CHLORINATION)

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A

Cl2
AlCl3 catalyst
warm

phenol --> phenylethanoate

CH3COCl 20 degrees

phenol --> sodium phenoxide

NaOH 20 degrees

aminobenzene --> benzenediazonium chloride

HNO2/HCl less than 5 degrees

benzenediazonium chloride -- yellow/orange azo compound

phenol NaOH less than 5 degrees