Periodicity Flashcards

1
Q

What decides which element is in which block?

A

Depending on which orbital the highest energy electrons are in, (e.g. s-orbital, p-orbital, d-orbital).

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2
Q

What is a group?

A

The vertical column of elements.

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3
Q

What happens to the reactivity of s-block metals as you go do down the group?

A

They get more reactive as you go down.

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4
Q

What happens to the reactivity of p-block non metals as you go down the group?

A

They get less reactive as you go down.

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5
Q

What is a period?

A

Horizontal rows of elements are called periods.

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6
Q

What is periodicity explained by?

A

The electron arrangement of an element.

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7
Q

What type of elements are those that are in group 1, 2, 3

A

Metals

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8
Q

What structures do the elements in group 1, 2 and 3 have.

A

Giant structures

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9
Q

What properties does silicon have?

A

They have some metallic properties and is therefore classed as a semi-metal.

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10
Q

Why do the melting and boiling points increase from sodium to aluminium?

A

The metallic bonding strength increases due increased ion charges and the amount of electrons increase.

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11
Q

What do the melting points of non-metals depend on?

A

Intermolecular forces

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12
Q

What does the atomic radii tell us?

A

The size of atoms.

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13
Q

What is the atomic radius affected by?

A

The type of bond.

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14
Q

Why do nobles gases not get compared in atomic radii?

A

They cannot form covalent bonds.

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15
Q

Why can you not measure the radius of a lone atom?

A

There is no clear point where electron cloud density drops to 0.

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16
Q

When can metals form covalent bonds?

A

In a gas phase.

17
Q

What happens to atomic radii across a period?

A

It decreases.

18
Q

Why does the atomic radii change across a period?

A

The higher amount of proton charge has a stronger pull on electrons to the nucleus.

19
Q

What happens to atomic radii down a group?

A

It increases.

20
Q

Why does the atomic radii increase down a group?

A

The outer electron is further away.

21
Q

What is the first ionization energy?

A

The energy needed to convert one mole of gaseous atoms into one mole of +1 positive charged gaseous ions.

22
Q

What is the ionization equation?

A

M(g) -> M+(g) + e-(g)
or
M(g) + e- -> M+(g) + 2e-(g)

23
Q

What happens to the first ionization energy down a group?

A

It decreases

24
Q

What happens to the first ionization energy across a group?

A

Generally increases.

25
Q

Why does the first ionization energy increase a group?

A

The amount of protons increases (stronger positive charge) but the electrons stays in the same level.

26
Q

Why does the first ionization energy decrease down a group?

A

More inner levels means increased shielding so the outer electrons are easier to remove.

27
Q

Why does oxygen have a lower ionization energy than nitrogen?

A

Nitrogen has half shell stability whereas oxygen doesn’t.

28
Q

Why does boron have a lower ionization energy than beryllium?

A

Removing an electron from boron means it loses the p orbital.

29
Q

Why does the successive ionization energy increase?

A

As you remove electrons the positive charge on the ion increases and the energy needed to remove an orbital is higher.