Physical Week 2 Flashcards

Bonding

1
Q

What is ionic bonding?

A

Ionic bonding occurs when metals and non-metals react, resulting in the transfer of electrons from metal atoms to non-metal atoms and the formation of ions. The resulting compound is called an ionic compound.

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2
Q

What are covalent bonds?

A

Covalent bonds occur when two non-metal atoms share a pair of electrons from their outer shells. This sharing of electrons allows each atom to complete its outer shell.

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3
Q

What is dative bonding?

A

Dative bonding, also known as coordinate covalent bonding, is a type of covalent bond where both electrons in the shared pair come from the same atom. It occurs when one atom donates a lone pair of electrons to another atom.

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4
Q

What is a hydroxonium ion?

A

The hydroxonium ion, also known as the hydronium ion or oxonium ion, is a positively charged ion composed of three hydrogen atoms and one oxygen atom. It is formed when a hydrogen ion (H+) attaches to a water molecule.

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5
Q

What is a compound?

A

A compound is a substance composed of two or more different elements chemically bonded together. Compounds have unique properties that are different from the elements that make them up.

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6
Q

What is an ionic compound?

A

An ionic compound is a compound formed through ionic bonding, where metal atoms donate electrons to non-metal atoms. The resulting compound consists of positively charged metal ions and negatively charged non-metal ions.

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7
Q

Can you give examples of covalent compounds?

A

Examples of covalent compounds include hydrogen (H2), chlorine (Cl2), methane (CH4), hydrogen chloride (HCl), water (H2O), and oxygen (O2). Ammonia (NH3), carbon dioxide (CO2), and ethene (C2H4) are also examples of covalent compounds.

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8
Q

What happens in dative covalent bonding?

A

In dative covalent bonding, only the hydrogen’s nucleus moves from chlorine to nitrogen, creating a negative chloride ion and a positive charge on the nitrogen atom.

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9
Q

What is the difference between ionic bonding and covalent bonding?

A

Ionic bonding involves the transfer of electrons between atoms, while covalent bonding involves the sharing of electrons.

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10
Q

How does dative bonding occur in NH3?

A

In dative bonding, a hydrogen ion is transferred from hydrogen chloride to the lone pair of electrons on the ammonia molecule, forming an ammonium ion (NH4+).

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11
Q

What is ionic bonding and when does it occur?

A

Ionic bonding occurs when metals and non-metals react, resulting in the transfer of electrons and the formation of ions.

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12
Q

What are the characteristics of materials with covalent bonds?

A

Materials with covalent bonds have strong bonds within molecules but weak forces of attraction between molecules, leading to low melting and boiling points.

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13
Q

What are dative covalent bonds?

A

Dative covalent bonds, also known as coordinate covalent bonds, occur when both electrons in a shared pair come from the same atom.

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14
Q

What happens once the ammonium ion is formed?

A

Once the ammonium ion is formed, it is indistinguishable from regular covalent bonds.

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15
Q

How do covalent bonds form?

A

Covalent bonds form when two non-metal atoms share a pair of electrons, completing their outer shells.

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16
Q

Can you provide examples of ionic bonding?

A

Examples of ionic bonding include reactions between magnesium and oxygen, calcium and chlorine, and sodium and chlorine.

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17
Q

What is conductivity?

A

Conductivity refers to the ability of a material to conduct heat or electricity. Metals are excellent conductors of both heat and electricity due to the presence of delocalized electrons.

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18
Q

What is a metallic bond?

A

The metallic bond is the attraction between free-moving (delocalized) electrons and positive metal ions. In metals, the outer shell electrons of metal atoms can move freely throughout the entire structure, creating a large structure.

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19
Q

What is ductility?

A

Ductility is the property of a material that allows it to be drawn into thin wires without breaking. Metals are ductile because their structure allows for the movement of ions, which enables the metal to be stretched into a wire shape

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20
Q

What is malleability?

A

Malleability is the property of a material that allows it to be bent, hammered, or pressed into different shapes without breaking. Most metals are malleable because their structure consists of layers of ions that can shift when external force is applied.

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21
Q

What is the effect of the metallic bond on the physical properties of metals?

A

It keeps metals in an orderly arrangement and gives them high melting and boiling points

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22
Q

How do metals create large structures?

A

Metals have large structures where electrons in the outer shells can move freely.

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23
Q

What is the property of metals that allows them to be bent without breaking?

A

Most metals are malleable and can be bent without breaking.

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24
Q

What happens to the ion layers in metals when they are bent or pressed?

A

The structure of metals allows ion layers to shift when the metal is bent or pressed.

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25
Q

How does the number of outer electrons affect the melting and boiling points of metals?

A

Metals with more outer electrons have higher melting and boiling points.

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26
Q

What property of metals makes them suitable for electrical cables?

A

Metals are ductile and can be pulled into wires, making them suitable for electrical cables.

27
Q

In what order do the melting and boiling points increase for Sodium, Magnesium, and Aluminium?

A

The melting and boiling points increase in the order: Sodium, Magnesium, Aluminium.

28
Q

What are bonding pairs?

A

Bonding pairs are pairs of electrons that are shared between atoms in a chemical bond. They contribute to the formation of covalent bonds, which are formed by the sharing of electrons between atoms.

29
Q

Describe the trigonal planar shape.

A

Trigonal planar is a molecular shape in which the atoms are arranged in a flat triangle. This shape occurs when there are three bonding pairs around the central atom with no lone pairs.

30
Q

Describe the shape of water.

A

Water (H2O) is a compound composed of two hydrogen atoms bonded to one oxygen atom. It has a bent or V-shaped molecular shape due to the presence of two bonding pairs and two lone pairs on the central oxygen atom.

31
Q

Describe the shape of ammonium.

A

The ammonium ion (NH4+) is a positively charged ion formed by the addition of a hydrogen ion (H+) to ammonia (NH3). It has a tetrahedral molecular shape, similar to methane, due to the presence of four bonding pairs around the central nitrogen atom.

32
Q

Describe the tetrahedral shape.

A

Tetrahedral is a molecular shape in which the atoms are arranged in a three-dimensional pyramid with a triangular base. This shape occurs when there are four bonding pairs around the central atom with no lone pairs.

33
Q

Describe the linear shape.

A

Linear is a molecular shape in which the atoms are arranged in a straight line. This shape occurs when there are only two atoms or when there are two bonding pairs around the central atom with no lone pairs.

34
Q

What are lone pairs?

A

Lone pairs are pairs of electrons that are not involved in bonding and are localized on a specific atom. They are also known as non-bonding pairs or unshared pairs.

35
Q

Describe the shape of ammonia.

A

Ammonia (NH3) is a compound composed of one nitrogen atom bonded to three hydrogen atoms. It has a tetrahedral molecular shape due to the presence of three bonding pairs and one lone pair on the central nitrogen atom.

36
Q

Describe the molecular shape of beryllium chloride (BeCl2).

A

Beryllium chloride (BeCl2) has a linear molecular shape with two bonding pairs positioned 180° apart.

37
Q

What is the molecular shape of water (H2O) and what is the bond angle?

A

Water (H2O) has a bent or V-shaped molecular shape with a bond angle of 104° caused by the repulsion between two lone pairs.

38
Q

What are the VSEPR geometries for simple molecules and ions?

A

The VSEPR geometries for simple molecules and ions include linear, trigonal planar, tetrahedral, trigonal pyramid, bent or angular, and square planar.

39
Q

What is the structure of the ammonium ion (NH4+) and why is it similar to methane?

A

The ammonium ion (NH4+) has a tetrahedral structure similar to methane due to its electronic arrangement.

40
Q

What is the molecular shape of boron trifluoride (BF3) and boron trichloride (BCl3)?

A

Boron trifluoride (BF3) and boron trichloride (BCl3) have a trigonal planar molecular shape with three pairs of electrons positioned 120° apart.

41
Q

What is the molecular shape of ammonia (NH3) and what is the bond angle?

A

Ammonia (NH3) has a tetrahedral molecular shape with a bond angle of 107° due to the repulsion between a lone pair and a bonding pair.

42
Q

How do lone pairs affect the bond angles in molecules and ions?

A

The presence of lone pairs can affect the bond angles in molecules and ions.

43
Q

If boron trifluoride (BF3) forms 3 bonds, similar to ammonia (NH3), what could be a possible effect on its molecular shape?

A

The presence of a lone pair could lead to more repulsion and alter the shape

44
Q

What are intramolecular forces?

A

Intramolecular forces are strong forces within a molecule, such as covalent bonds. These forces mainly affect the chemical properties of a compound.

45
Q

What are intermolecular forces?

A

Intermolecular forces are relatively weak attractions between molecules. They influence physical properties like boiling point, melting point, solubility, and viscosity.

46
Q

What are Van der Waals forces?

A

Van der Waals forces, also referred to as London forces or induced dipole forces, are a type of intermolecular force. These forces arise due to temporary changes in electron density, leading to the formation of temporary dipoles in molecules

47
Q

What are permanent dipole-dipole forces?

A

Permanent dipole-dipole forces are a type of intermolecular force that occurs between polar molecules. These forces are stronger than van der Waals forces and result from the attraction between the partial positive end of one molecule and the partial negative end of another molecule.

48
Q

What is hydrogen bonding?

A

Hydrogen bonding is a type of intermolecular force that occurs in compounds containing a hydrogen atom bonded to nitrogen, oxygen, or fluorine. These electronegative atoms must also have an available lone pair of electrons.

49
Q

What is a non-polar bond?

A

A non-polar bond is a covalent bond between atoms with equal or very similar electronegativities. The electron distribution in the bond is symmetrical, resulting in no permanent dipole across the molecule.

50
Q

What is a polar bond?

A

A polar bond is a covalent bond between elements with different electronegativities. The electron distribution in the bond is unsymmetrical, resulting in a permanent dipole across the molecule.

51
Q

What is electronegativity?

A

Electronegativity is the ability of an atom to attract the pair of electrons in a covalent bond towards itself. It is measured on the Pauling scale, which ranges from 0 to 4.

52
Q

If you have a molecule of 1-chloropropane and a molecule of pentane, which one would have a higher boiling point and why?

A

1-chloropropane would have a higher boiling point because it has both van der Waals forces and permanent dipole attractions, which are stronger than the van der Waals forces in pentane.

53
Q

What are intermolecular forces and how do they differ from intramolecular forces?

A

Intermolecular forces are weak attractions between molecules that influence physical properties, while intramolecular forces are strong forces within a molecule that affect chemical properties.

54
Q

What explains the increasing boiling points in the alkane homologous series?

A

The increasing boiling points in the alkane homologous series can be explained by the growing number of electrons and the shape of the molecule, leading to stronger van der Waals forces.

55
Q

If you were to compare the boiling points of H2O and H2S, which one would have a higher boiling point and why?

A

H2O would have a higher boiling point because it can form two hydrogen bonds due to the electronegative oxygen atom having two lone pairs of electrons, resulting in stronger hydrogen bonding.

56
Q

What is the significance of hydrogen bonding in intermolecular forces?

A

Hydrogen bonding is the strongest intermolecular force, contributing to higher boiling points and solubility in compounds like water and ethanol.

57
Q

How does the arrangement of polar bonds in a molecule determine its polarity?

A

The presence of polar bonds in a molecule can result in a permanent dipole, making the molecule polar. However, if the polar bonds are arranged symmetrically, the molecule can be non-polar.

58
Q

What are some effects of hydrogen bonding in substances?

A

Hydrogen bonding leads to the formation of regular structures in substances like ice and dimer formation in compounds like ethanoic acid.

59
Q

What is electronegativity and how does it relate to covalent bonds?

A

Electronegativity is the ability of an atom to attract electrons towards itself in a covalent bond. Polar bonds result from a difference in electronegativity, leading to a permanent dipole across the molecule.

60
Q

Why does iodine not conduct electricity and have low solubility in water?

A

Iodine does not conduct electricity and has low solubility in water due to its lack of charged particles and non-polar nature.

61
Q

What are the three main types of intermolecular forces and how are van der Waals forces influenced?

A

The three main types of intermolecular forces are van der Waals forces, permanent dipole-dipole forces, and hydrogen bonding. Van der Waals forces are influenced by the number of electrons in a molecule and are responsible for high melting and boiling points in molecular crystals like I2.

62
Q

What causes the attraction in hydrogen bonding?

A

Hydrogen bonding is characterised by the attraction between the small hydrogen atom and oxygen, nitrogen, or fluorine atoms due to their electronegativity difference.

63
Q

What are permanent dipole-dipole forces and how do they affect boiling points?

A

Permanent dipole-dipole forces are intermolecular forces, which are stronger than van der Waals forces, and result in compounds with higher boiling points.

64
Q
A