Quiz 1 Flashcards
(56 cards)
Henry David Thoreau Quote from Walden
“A lake is a landscapes most beautiful and expressive feature.
It is earth’s eye; looking into which the beholder measures the depth of his own nature.”
How much water is there on the planet?
1.37 billion km2 but 97.6 is in the oceans as salt water
Where is water stored? (5)
Most is in oceans
Then glaciers
Then ground water
Glaciers hold the majority of freshwater (for now) though they’re melting at an alarming rate
About 0.009% is stored in lakes
What are some characteristics of water (10)
Found even on Mars Colourless Odourless Tasteless Easier to melt ice at higher pressure Easier to boil water at lower pressure Ice is lighter than water High specific heat capacity Can dissolve substances better than any other liquid It is the only substance that is found in all three states at the temperatures normally found on earth
What is the importance of water? (3)
Water influences the:
physical
chemical
and metabolic
properties and dynamics of freshwater ecosystems
What is the benefit of water’s thermal density properties in terms of life? (2)
Because water can absorb and release heat energy from the environment causing it to change state, it provides a tempered environment in which temperature extremes are moderated relative to in terrestrial ecosystems
These properties, coupled with viscosity, have resulted in the development of a large number of adaptations for aquatic life
What is water?
Made up of H2O molecules (O molecules having 8 protons and 8 elections, and (H molecules having 1 proton and 1 electron)
How does water get it’s characteristics? (7)
Lone pair electrons are electrons that are not suited with another atom in a covalent bond
Only the oxygen atom in water has lone pairs
The oxygen atom has 3 lone pairs, 1 of which is in covalent bonds with the hydrogen atoms, and 2 of which are spread around the oxygen atom in a tetrahedral form
Because oxygen has 8 protons and hydrogen only has one, these negatively charged pairs are attracted to the upper side of the molecule
Because the highly charged lone pairs repellent each other, they push the hydrogen atoms closer together
This gives the molecule a bent structure (104.5 degree angle between hydrogen atoms) and is the reason for waters unique characteristics
Is it correct to think of water as just H2O? (2)
No - it ya made up of different oxides, isotopes of oxygen; and different ionic forms
There are at least 33 different combinations that make up water
Covalent bonds
Sharing of electrons between atoms to create a molecule
Hydrogen bonds (4)
Interaction involving a hydrogen atom between molecules when positive hydrogen side of molecule attracts to negative side of oxygen molecule
Water does not exist as a single H2O molecule, but rather many molecules linked together by hydrogen bonding
Are weaker than covalent bonds but become strong in water because there are so many of them
Hydrogen bonding give water its gel-like properties, as bonds can break and reform extremely rapidly
Unusual properties of water caused by hydrogen bonding (4)
As molecular weight decreases in alcohol and hydrides, so does its boiling point
But in water, it’s molecular weight is lowest but has the highest boiling point - so it doesn’t fit this pattern
To put into perspective, CH4 has a molecular weight similar to water (16 to 18), but it’s boiling point is -161, while water’s is 100
In essence, water melts and boils at much higher temperatures than other covalently bound but non-polar compounds with similar molecular weight (due to hydrogen bonding)
Why is water a good solvent?
Because of its negatively and positively charged “clouds” (oxygen negative, hydrogen positive), it dissolves polar solutes easily (eg. Sodium chloride crystal is broken into positive sodium ion which bonds to negative oxygen side, and negative chloride ion which bonds to positive hydrogen side)
Bonding and state of water (3)
In liquid, each molecule is bonded to approximately 3.4 other water molecules
In gas, there is no bonding
In solid, each molecule is bonded to 4 other water molecules giving ice a tetrahedron shape
(Eg. Cube)
Why is ice less dense than water? (4)
As water freezes, tetrahedrons come closer together and crystallize into a six-ring or hexagonal structure
Unlike most substances, when water is near freezing, instead of continuing to contract, it expands slightly from about 4 degrees to 0 degrees) (Eg. Bottle of water will explode in freezer)
This is due to hydrogen bonds, as they extend the molecules to their fullest distance from each other
This makes ice less dense than water, allowing it to float (bond angle 106.6 rather than 104.45)
How is the latent heat of fusion for ice to water and water to vapour different? (4)
The latent heat of fusion for ice to water is low (80 calories per gram)
As ice heats up, the latent heat is focused on the phase change and so the temperature does not change (beneficial for us as the ice caps melt, because the water does not increase temp which would speed up the process) - this is due to the higher bond angles found in ice making the hydrogen bonds easier to break (giving ice a lower latent heat needed to melt)
The latent heat of fusion of water to vapour is high (540 captives per gram)
So when water is changing to vapour, the energy is moved away in the steam and this is why steam burns hurt so badly (so much latent heat being transferred)
Lake facts (5)
Lakes cover less than 2% of earth’s surface
Only 20 lakes in the world are deeper than 400m
20% of all the worlds fresh water is in Lake Baikal, Siberia
Caspian Sea is biggest in area (but debatable whether it’s considered a lake because it’s salty)
Second is Lakes Michigan and Heron
What is the largest contiguous mass of freshwater lakes on earth? (2)
The Great Lakes
Collectively have just over the volume of water of Baikal
Which lake has the greatest surface area of any lake on earth?
Lake Superior
Which lake has the greatest volume of fresh water on earth?
Lake Baikal
What are the types of lake formation? (11)
Tectonic basin formation Volcanic basin formation Lakes formed by landslides Lakes formed by wind Lakes formed by rivers Lakes formed by glacial activity Solution lakes Lakes associated with shorelines Lakes formed by meteor impact Biogenic lakes Anthropogenic lakes
Tectonic basin formation lakes (4)
Tectonic basins are depressions formed by movements of the earth’s crust
Can be due to:
- Tectonic uplift: causing marine sea bed to be isolated into very large lake basins
Ex: Caspian Sea, Great Salt Lakes in Utah
- Tectonic down faulting: tectonic basins formed as a result of faulting causing depressions called Grabens
Ex: Baikal, Lake Tahoe
Grabens and horsts
During tectonic faulting, horsts are the upfaulted ridges and grabens are the downfaulted troughs that fill with water and become lakes
Why do tectonic downfaulting lakes have a large number of endemic species? (2)
Because they are very old
Over 80% of the plant and animal species in Baikal are endemic