Rates QQ Trade Flashcards

(30 cards)

1
Q

The minimum amount of energy needed for the particles to react is called the

A

Activation energy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Name the two things the rate of a reaction depends

A

proper orientation
min energy- EA

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What factors affect the rate of reactions?

A

concentration, surface area, temperature, catalyst, and pressure

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

As the reaction progresses, what happens to the concentration of reactants

A

it decreases

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

if a reaction involves HCl, give 2 possible ways to monitor the rate

A

pH and conductivity

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

what is the mathematical expression of rate of reaction

A

Rate=∆[A]/ ∆t

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

The change in concentration over a given time is called

A

average rate

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

the change in concentration at a given time is called

A

instantaneous rate

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

How does an increase in temperature increase the rate of the reaction

A

increase kinetic energy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

A substance that increases the rate of a chemical reaction without being used up

A

catalyst

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

how does a catalyst affect the rate of a reaction

A

reduce activation energy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

which graph shows as the temperature increases, a larger population of molecules has higher energy

A

Maxwell-boltzmann distributions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

how do you represent the activation energy on a graph

A

from the starting point to the hump (activated complex)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

what is the highest point on the potential energy graph called

A

transition state

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

what is the name of the species that is an intermediate between reactants and products in a chemical reaction

A

activated complex

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

what is the sequence of events that describes the actual process by which reactants become products

A

reaction mechanism

17
Q

each single step in a reaction is called

A

elementary step

18
Q

what is the name of a reaction that has 3 molecules in its elementary step or slow step

19
Q

what is the slow step in a reaction called?

A

rate determining step, RDS

20
Q

the species that is formed in one reaction and then used up in another is called

21
Q

the species that is put in one step and regenerated at the end of the reaction is called

22
Q

if a solid reactant is crushed, the reaction rate increases, what factor did this

23
Q

what is the unit for rate

24
Q

what is the rate expression for the reaction 2A -> 3B?

A

Rate = -1∆[A]/2∆t = 1∆[B]/3∆t

25
if the concentration of a reactant does not affect the rate, what is the order of the reaction?
zero order
26
what does a first order reaction mean
concentration affects the rate -> directly, proportional
27
what does a second order reaction mean
rate is affected by concentration squared
28
factors that affect reaction rates
-concentration of reactants (as [] increases so does likelihood of collisions) -temperature (high temp=more collision) -surface area (more surface area=more collisions= higher rate) -pressure (for gasses, more pressure=more collisions=higher rate) -catalyst (decreases activation energy of reaction)
29
Rate equation and units
Rate= ∆[]/∆T Mol/Lsec
30
Measuring reaction rates
1. monitoring mass - when gas is released the reduction in mass of the product can be measured (Rate =∆m/∆t) 2. volume - rxns that generate gas, the volume of gas can be monitored (Rate=∆vol/∆t) 3. pH - when an acid or base is present, then changes in pH can be measure (Rate= ∆pH/∆T) 4. conductivity - dissolved ions in aqueous solution conduct electricity 5. pressure -for rxns involving gasses on both sides of equation. Change in moles, pressure censor used to measure ∆ in pressure (Rate=∆p/∆t) 6. Absorbance -for coloured solutions, monitor absorption of light using spectometry -absorption of light is directly related to concentration (Rate=∆absorption/∆t)