Reagents Flashcards

1
Q

What are the essential conditions for free radical substitution

A

UV light

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2
Q

What are the essential conditions for nucleophilic substitution of haloalkanes

A

Warm aqueous NaOH (or KOH)

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3
Q

What conditions are needed for addition Polymerisation of alkenes

A

High temp
High pressure
Initiator/catalyst

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4
Q

What 2 conditions are needed for a hydrogenation reaction of alkene - breaks double bond (electrophilic addition)

A

150*c

Nickel catalyst

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5
Q

What happens in hydration of alkenes

A

H2O is added across double bond

Alkene -> alcohol

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6
Q

What happens in electrophilic addition

A
Alkene -> alkane 
Hydrogen added (H2, HBr)
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7
Q

4 conditions needed for hydration of alkenes

A

High pressure (60-70atm)
300*c
H3PO4 catalyst (phosphoric acid catalyst)
Steam

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8
Q

What’s test for alkenes

A

Bromine water goes from orange -> colourless if positive

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9
Q

What is used in simple oxidation reactions of alcohols as an oxidant agent

A

Acidified potassium dichromate (VI) K2CrO7
Or
H2SO4

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10
Q

If the K2Cr7O7 oxidises something what would the colour change be

A

Orange -> green

Oxidation must have occurred

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11
Q

What does a 1y alcohol oxidise to

A

Aldehyde -> Carboxylic acid

-CHO -COOH

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12
Q

What does a 2y alcohol oxidise to

A

Ketone C=O

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13
Q

What conditions are used for elimination of alcohols back to alkenes (dehydration)

A

Hot concentrated sulphuric/phosphoric acids

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