Redox Flashcards
(26 cards)
What is the oxidation number of any uncombined element ?
0
What is the oxidation number of combined oxygen ?
-2
What is the oxidation number of combined hydrogen ?
+1
What is the oxidation number of a simple ion ?
the charge on the ion
What is the oxidation number of combined fluorine ?
-1
What is the oxidation number of hydrogen in a metal hydride ?
-1
What is the oxidation number of oxygen in a peroxide ?
-1
What is the oxidation number of oxygen when bonded to fluorine ?
+2
What is the oxidation number of a transition metal ?
the number in the brackets
What is oxidation in terms of electron transfer ?
loss of electrons
What is oxidation in terms of oxidation number ?
an increase in oxidation number
What is reduction in terms of electron transfer ?
gain of electrons
What is reduction in terms of oxidation number ?
a decrease in oxidation number
What is a redox reaction ?
a reaction that involves both oxidation and reduction
What is an oxidising agent ?
a specie that oxidises another specie and itself gets reduces
What is a reducing agent ?
a specie that reduces another specie and itself gets oxidised
What is disproportionation ?
where the same element is oxidised or reduced in a redox reaction
What is the reagent, observation and equation in the test for carbonate ions ?
- reagent : nitric acid
- observation : bubbles of gas (can be bubbles through limewater to prove it is CO2)
- 2H+ (aq) + CO3 2- (aq) => H2O (l) + CO2 (g)
What is the reagent, observation and equation in the test for sulphate ions ?
- reagent : barium nitrate
- observation : white precipitate
- Ba 2+ (aq) + SO4 2- (aq) => BaSO4 (s)
Why must you do the test for carbonates before the test for sulphates ?
because you can get a false positive if CO3 2- is present as barium carbonate is produced, which is insoluble
What is the reagent, observation and equation in the test for ammonium ions ?
- reagent : hydroxide ions
- observation : damp red litmus paper turns blue
- NH4+ (aq) + OH- (aq) => NH3 (g) + H2O (l)
What is the order for tests in qualitative analysis ?
- carbonates
- sulphates
- ammonium
- halides
Which acid should be used for the carbonate test if you may go on to test for halides or sulphates and why ?
nitric acid, as you are testing for sulphates and halides, so you can’t use hydrochloric or sulphuric acid
Why is it important to remove carbonates by adding acid before testing for sulphates ?
because carbonates may give a false positive when barium nitrate is added