Redox Flashcards

(26 cards)

1
Q

What is the oxidation number of any uncombined element ?

A

0

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2
Q

What is the oxidation number of combined oxygen ?

A

-2

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3
Q

What is the oxidation number of combined hydrogen ?

A

+1

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4
Q

What is the oxidation number of a simple ion ?

A

the charge on the ion

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5
Q

What is the oxidation number of combined fluorine ?

A

-1

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6
Q

What is the oxidation number of hydrogen in a metal hydride ?

A

-1

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7
Q

What is the oxidation number of oxygen in a peroxide ?

A

-1

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8
Q

What is the oxidation number of oxygen when bonded to fluorine ?

A

+2

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9
Q

What is the oxidation number of a transition metal ?

A

the number in the brackets

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10
Q

What is oxidation in terms of electron transfer ?

A

loss of electrons

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11
Q

What is oxidation in terms of oxidation number ?

A

an increase in oxidation number

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12
Q

What is reduction in terms of electron transfer ?

A

gain of electrons

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13
Q

What is reduction in terms of oxidation number ?

A

a decrease in oxidation number

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14
Q

What is a redox reaction ?

A

a reaction that involves both oxidation and reduction

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15
Q

What is an oxidising agent ?

A

a specie that oxidises another specie and itself gets reduces

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15
Q

What is a reducing agent ?

A

a specie that reduces another specie and itself gets oxidised

16
Q

What is disproportionation ?

A

where the same element is oxidised or reduced in a redox reaction

17
Q

What is the reagent, observation and equation in the test for carbonate ions ?

A
  • reagent : nitric acid
  • observation : bubbles of gas (can be bubbles through limewater to prove it is CO2)
  • 2H+ (aq) + CO3 2- (aq) => H2O (l) + CO2 (g)
18
Q

What is the reagent, observation and equation in the test for sulphate ions ?

A
  • reagent : barium nitrate
  • observation : white precipitate
  • Ba 2+ (aq) + SO4 2- (aq) => BaSO4 (s)
19
Q

Why must you do the test for carbonates before the test for sulphates ?

A

because you can get a false positive if CO3 2- is present as barium carbonate is produced, which is insoluble

20
Q

What is the reagent, observation and equation in the test for ammonium ions ?

A
  • reagent : hydroxide ions
  • observation : damp red litmus paper turns blue
  • NH4+ (aq) + OH- (aq) => NH3 (g) + H2O (l)
21
Q

What is the order for tests in qualitative analysis ?

A
  1. carbonates
  2. sulphates
  3. ammonium
  4. halides
22
Q

Which acid should be used for the carbonate test if you may go on to test for halides or sulphates and why ?

A

nitric acid, as you are testing for sulphates and halides, so you can’t use hydrochloric or sulphuric acid

23
Q

Why is it important to remove carbonates by adding acid before testing for sulphates ?

A

because carbonates may give a false positive when barium nitrate is added

24
Which barium solution should be used for the sulphate test if you may go on to test for halides , and why ?
barium nitrate, as you are testing for halides so you can't use barium chloride
25
Why is the halide test done last ?
to rule out the carbonates and sulphates first as they also give a white precipitate