Section 7.2- Electrons and the Structure of the Atom Flashcards

1
Q

a more precise instrument that can be used in the laboratory to separate the colors even further and study them in more detail

A

spectrometer

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2
Q

a spectrum containing only certain colors (wavelengths) is a

A

line spectrum

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3
Q

a spectrum containing the complete array of colors, is a

A

continuous spectrum

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4
Q

allowed scientists to study elements in an entirely new way

A

discovery of line spectra

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5
Q

virtual fingerprint

A

line spectrum

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6
Q

presented the atom as a miniature solar system with electrons orbiting like planets

A

Rutherford’s planetary model

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7
Q

the problem withe Rutherford’s planetary model

A

the electron would spiral closer to the nucleus as it gradually lost energy, eventually colliding with the nucleus and destroying the atom

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8
Q

proposed a new model of atomic structure that explains both why the lines in the hydrogen spectrum are mathematically related and why the atom does not self-destruct

A

Niels Bohr

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9
Q

using aspects of Planck’s quantum theory, Bohr explained that the electron in the hydrogen atom can move about the nucleus only in specific orbits called

A

energy levels

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10
Q

only certain orbits are allowed; the energy of the allowed orbits is _________________

A

quantized (restricted to certain values)

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11
Q

equation for energy quantized

A

E = -J (a constant) / nsquared (quantum number)

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12
Q

the lowest energy state

A

ground state

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13
Q

the ground state of the hydrogen atom is the state where

A

n = 1

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14
Q

all other higher-energy states are said to be

A

excited states

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15
Q

the ______________ energy state possible is the most stable

A

lowest

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16
Q

gives us the energy of the photon emitted in a transition

A

E2 - E1 = hf

17
Q

both ______________ and _________________ are quantized.

A

absorptions
emissions

19
Q

problem with Bohr’s model

A

it fails to account for the spectra of atoms containing more than one electron

20
Q

a French physicist who proposed that since radiation has properties of particles, then particles in motion should have properties of waves

A

Louis de Broglie

21
Q

the waves de Broglie proposed

A

matter waves

22
Q

matter waves cannot move at the

A

speed of light

23
Q

the equations for the matter waves wavelength

A

lambda = h (Planck’s constant) / mv

24
Q

the electron can be shown to behave as a ____________ as well as a _____________

A

wave and particle

25
applies to all waves and all particles, though for macroscopic objects the wave properties are too small to measure and are ignored
wave-particle duality
26
combined the Bohr model with de Broglie's hypothesis to propose the wave- mechanical model
Erwin Schrodinger
27
according to this model of the atom, an electron in an atom behaves as a three-dimensional matter wave containing an integral number of wavelengths in an orbit
Schrodinger's wave-mechanical model
28
a three-dimensional matter wave containing an integral number of wavelengths in an orbit is known as a
standing wave
29
stated the uncertainty principle
Werner Heisenberg
30
states that it is impossible to simultaneously determine the momentum (mass times velocity) and the position of an electron with precision; either momentum or position may be precisely measured, but not both
uncertainty principle
31
in Born's interpretation, electrons are treated as pointlike particles rather than waves but are not regarded as having definite orbits through space; instead, they are said to move in regions called
orbitals
32
a region of space in which there is a high probability of finding the electron
orbital
33
a definite path in space
orbit
34
Born's interpretation of the wave-mechanical model is sometimes called the
electron-cloud model
35
Born's interpretation is simply another way of looking at ____________________
Schrodinger's equations