Shikimate Pathway Flashcards
(46 cards)
Building block of shikimate pathway
C6C3 phenylpropane unit
Central intermediate in shikimate pathway
Shikimic acid
Building block for alkaloidal structures
L-Trp
Precursors of L-DOPA and DOPAchrome
L-Phe and L-Tyr
Precursor of catecholamines
L-dopa
Precursor of melanin
Dopachrome
Precursor of tannins
Gallic acid
Plant polyphenols which has the ability to precipitate proteins
Tannins
Botanical origin of witch hazel leaves
Hamamelis virginiana
Botanical origin of nutgall
Rhus chinensis
Botanical origin of mangrove
Rhizophora mangle
Color formed upon rxn with ferric salts
Dark blue (H) to greenish black (NH)
Color formed upon rxn with potassium ferricyanide and ammonia
Deep red
Types of tannins
Hydrolyzable and non-hydrolyzable
Other name for hydrolyzable tannins
Pyrogallotannins
Intermediate where pyrogallotannins are derived
Dehydroshikimic acid
Classes of hydrolyzable tannins
Gallotannins and ellagitannins
Esters of gallic acid with polyalcohol typically glucose
Gallotannins
Hexahydroxydiphenic acid esters by oxidative coupling of neighboring gallic units attached to D-glucose
Ellagitannins
Gallotannins arise from ?
Quinic acid
Other names for non-hydrolyzable tannins
Condensed tannins, proanthocyanidins, pycnogenols, leucoanthocyanidins
Non-hydrolyzable are derived from ?
Flavonoid precursors
Product of polymerization of nonhydrolyzable tannins
Phlobaphenes
Test for total tannin analysis
Goldbeater’s skin test/Heme analysis