Test 1 Flashcards

(47 cards)

1
Q

Two important aspects of identifying a biomaterial to be used in the human body are functional performance and _____________ .

A

Biocompatibillity

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2
Q

________ are widely used as biomaterials for their strength and toughness

A

metals

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3
Q

give 3 examples of metals used throughout the human body

A
  1. stainless steel 316L 2. titanium 3. cobalt alloys
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4
Q

what is the most common type of medical grade stainless steel? Name 3 elements in this type of stainless steel

A

stainless steel 316L iron, chromium, nickel

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5
Q

state 3 physical properties of metals that make them attractive for their use as a metallic biomaterial?

A

Ductile, high melting point, luster, malleable

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6
Q

what element increases the formation of carbon dioxide (Cr23C6) in 316L stainless steel?

A

chromium

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7
Q

name the overall classification of materials that could potential used as biomaterials

A

metals, ceramics, composites, polymers

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8
Q

give 3 examples of materials that can be used as dental metals

A

Amalgam, gold and gold alloy, nitinol

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9
Q

which of these metallic biomaterials has the best corrosion resistance; which of these metallic biomaterials cobalt alloys, stainless steel or pure titanium?

A

pure titanium

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10
Q

why is pure gold not useable in dental applications? What is added to it to make it a better dental biomaterial

A

pure gold is too soft add platinum

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11
Q

why is it advisable to reduce carbon content in medical grade stainless steel material

A

reduce carbide formation at grain boundary carbide impairs formation of surface oxide

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12
Q

what is the main advantage of using a titanium alloy in bone as opposed to any other metal

A

permits bone growth at the interface

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13
Q

what is purpose of adding tungsten of nickel to cobalt based alloys

A

improve machinability and fabrication

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14
Q

state 3 reasons why amalgam is preferred as a dental biomaterial?

A

stable strong inexpensive and endurbale

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15
Q

metalls are widely used as biomaterials due to their ______ & ___________

A

strength and toughness

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16
Q

list four metallic implants materials and explain the composition properties and potential applications for one of them

A

Cobalt chromium alloys- Co:58-69%, Cr: 27-30%, Mo: 5-7% titanium based alloys- Ti: 89%, Al: 6%, V: 4% 316L stainless steel- 60-65% iron, 17-19% chromium, 12-14% nickel nitinol- Nickel and titanium aplication: bone plates, stents and orthodontic wires

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17
Q

what is biocompatibility

A

does not elicit a negative response with the body

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18
Q

What is nitinol

A

an alloy of Nickel and titanium also is a shape memory alloy

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19
Q

name 3 types of medical devices

A

drug delivery cardiovascular devices orthopedic

20
Q

state 2 ways in which atoms of metals mix to form alloys

A

substitution and intersticial

21
Q

describe shape memory alloys

A

have the ability to return to a predetermined shape when heated

22
Q

what is the outer layer that protects a metal from corrosion

A

surface oxides

23
Q

although several types of stainless steel are available for implant use, in practice the most common is grade 2, _________ stainless steel. This stainless steel alloy is composed predominantly ____, which makes up approximately 60-65%, plus addition of ____, makes up 17-20% of the alloy. Additionally, approximately 12-14% of the alloy is comprised of _____. In order to reduce the possibility of in vivo corrosion only trace amounts less than 0.03% of ____ are found in the alloy.

A

316L iron chromium nickel carbon

24
Q

Co-Cr-Mo alloys, ASTM F75 or ASTM F799 are mostly made up of Cobalt comprising _______%. also in the compound is approx _______% of chromium and roughly ____% of molybdenum

A

Co:58-69% Cr: 27-30% Mo: 5-7%

25
define unit cell as it relates to metallic crystal structure
smallest repetive volume which contains the complete lattice pattern of a crystal and metals are crystalline solids
26
state and describe 3 tpyes of imperfections/ defects in the metallic crystal structure
vacancy atoms- empty spaces where an atom is missing interstitial-extra atoms are positioned between atomic sites dislocations- line defects, slip between crystal planes result when dislocations move
27
state and describe 2 metal fabrication methods
Forming- forging, rolling, drawing, extrusion casting- mold is filled with a metal joining- powder metallurgy, welding
28
In an electrochemical redox reaction, loss of electrons is _______ and a gain of electron is \_\_\_\_\_\_,
loss of electron is OXIDATION gain of electrons is REDUCTION
29
describe the mechanism of metallic corrosion
corroded state is preferred since lowest energy state metal atoms ionize go into solution and combine with oxygen metal flakes off
30
define galvanic corrosion
two different metals/ alloys that are in close proximity in an electrolytic environment
31
what is corrosion
gradual wearing away process
32
what are the 2 primary factors that drive metallic corrosion
1. thermodynamic driving forces (reduction/oxidation) 2. kinetic barriers
33
what substance is oxidized and which substance is reduced in the formation of rust? 4Fe+2 + O2 + 8H2O → 2Fe2O3H2O + 8H+
Oxidized: Fe reduced: oxygen
34
what is the main function of the oxide layer on the surface of a metal
to prevent corrosion and rusting
35
state and describe 3 types of corrosion
galvanic- 2 different metals/ alloys that are in close proximity in an electrolytic environment crevice- found in the crevices or deep, narrow flaws uniform attack- general corrosion that is evenly distributed over entire corrosion region
36
name and describe 2 basic reactions associated with corrosion
Ionization: formation of metallic cations under acidic or reducing conditions oxidation: reaction of metal with oxygen
37
how does galvanic corrosion occur
metals/ alloys in close proximity with electrolytic environment
38
which is the reducing agent and which is the oxidizing agent in the reaction below? Cu + 2Ag+ → Cu+2 + 2 Ag
oxidation: Cu to Cu2+ reduction: 2Ag+ to 2 Ag
39
In the galvanic series which (gold, magnesium, and titanium) is considered the most active metals in seawater?
magnesium
40
which type of corrosion occurs when 2 different metals/alloys are in close proximity in an electrolytic environment? A. Pitting corrosion B. Crevice corrosion C. galvanic corrosion D. Intergranular corrosion
C. galvanic corrosion
41
what is fretting corrosion
wear process due to relative motions in highly loaded devices exaggerated by corrosive environment
42
what can one do to prevent corrosion
use appropiate metals minimize pits and crevices avoid implantation of dissimilar metals
43
describe uniform attack corrosion
general corrosion that is evenly distributed over entire corrosion region
44
explain deposit corrosion mechanism
foreign substances with moisture which come from the environment adhearing to a surface of a metal cause the deposit corrosion because of the lack of oxygen under the deposit.
45
what is the difference between galvanic and fretting corrosion
galvanic corrosion is when 2 different metals/ alloys are in close proximity with electrolytic environment fretting corrosion is the wear process due to relative motion in highly loaded devices exaggerated by corrosive environment
46
describe the possible effects of corrosion of medical devices
biocompatibility mechanical integrity aesthetics
47
what are some of the advantages and disadvantages of the use of magnesium for implant material applications
_Advantages:_ * biodegradable * lightweight * biocompatibility _disadvantages:_ * low corrosion resistance * fast hydrogen evolution * degradation occurs before end of healing