Test 13 Flashcards

(52 cards)

1
Q

The branch of science that studies the transfer of energy during chemical reactions or phase changes

A

Thermochemistry

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2
Q

Expresses the average kinetic energy in the particles of a sample

A

Temperature

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3
Q

An insulated container, similar to a thermos, in which a thermometer detects the enthalpy that occurs during a chemical reaction

A

Calorimeter

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4
Q

The heat that produces a phase change

A

Latent heat

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5
Q

The heat that produces a temperature change in the substance when applied

A

Sensible heat

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6
Q

Why do enthalpies of vaporization differ widely?

A

The strength of intermolecular attractions in different liquids vary

Higher value means stronger intermolecular attractions

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7
Q

The amount of thermal energy required to raise the temperature of 1 g of the substance by 1°C

A

Specific heat Csp

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8
Q

Substances with__specific heats require large amounts of energy for a given temperature change and will change temperature only slowly

A

High

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9
Q

Which retains heat longer, substances with high specific heat values or low specific heat values?

A

High specific heat values

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10
Q

Why do the products in an exothermic reaction have a lower enthalpy than the reactants

A

Because energy is released during the reaction

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11
Q

If the reaction is endothermic the energy will be a

A

Reactant

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12
Q

If the reaction is exothermic the energy will be a

A

Product

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13
Q

A negative enthalpy of reaction value signifies what kind of reaction?

A

Exothermic

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14
Q

The enthalpy of reaction of a reverse reaction has the__magnitude but the__sign of the delta H of the forward reaction

A

Same

Opposite

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15
Q

The enthalpy change for the reaction that produces one mole of a compound in its standard state from its elements in their standard states

A

Standard molar enthalpy of formation /\ H °f

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16
Q

What does the degree symbol of /\ H °f mean?

A

It signifies that this delta H refers to standard conditions

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17
Q

Energy released as heat by the complete burning of one mole of a substance at standard conditions

A

Standard molar enthalpy of combustion /\ H °c

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18
Q

r States that the enthalpy change of a reaction equals the sum of the enthalpy changes for each step of the process

A

Hess’s Law

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19
Q

What is always required to break bonds

A

Energy

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20
Q

Entropy measures

A

Randomness of a system

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21
Q

Entropy __as temperature increases

22
Q

Delta H represents

23
Q

Delta S represents

24
Q

What is the formula for calculating free energy change (/\ G)

25
What does a negative G indicate
A decline in free energy and it signifies that a reaction may occur spontaneously The reaction is favorable
26
J to KJ
Move decimal three places to the left
27
KJ to J
move decimal three places to the right
28
Must convert from
Celsius to Kelvin
29
Formula for Celsius to Kelvin
°C + 273 = K
30
Why does drink stay hot longer than pop tart
Water has a higher specific heat than a pop tart
31
When determining free energy change the temperature must be in
K
32
Symbol for free energy
G
33
G measures
Favorability of reactions considering both entropy and enthalpy
34
And spontaneous natural processes entropy tends to__and enthalpy __
Increases Decreases
35
If it's going from weaker bonds to stronger bonds, it is
Exothermic
36
Gas has the__entropy
Most
37
Formula for /\H°reaction
/\H°reaction= E /\H products- E /\H reactants
38
Formula for /\S°reaction
/\S°reaction= E /\S products- E /\S reactants
39
Used to determine whether increase or decrease in entropy
Formula for /\S
40
Formula for /\G
/\G= /\H- T /\S
41
/\H- /\S+
/\G - always
42
/\H- /\S-
/\G- at low temperatures
43
/\H+ /\S+
/\G - at high temperatures
44
/\H+ /\S-
/\G + always
45
The measure of the dispersal of energy in a system; the net decrease of usable energy in the system for a given temperature and quantity of matter
Entropy S
46
-/\H=
Exothermic
47
+/\H=
Endothermic
48
-/\S=
Decrease in entropy
49
+/\S=
Increase in entropy
50
The quantity of thermal energy required to convert one mole of a liquid at its boiling point to its vapor at the same temperature
Molar enthalpy of vaporization /\H vap
51
A chemical equation that shows the reactants, products, and amount of energy that is released or absorbed as heat
Thermochemical equation
52
Standard state
25°C (298 K), and one atm of pressure