Tests for Anions Flashcards
(11 cards)
carbonate test
- add dilute hydrochloric acid to your test sample
- if carbonates are present then carbon dioxide will be released by effervescence
- if this occurs, bubble the gas through limewater (to prevent false positives) and if carbonate ions were present the limewater will turn cloudy
carbonate test word and symbol equation
carbonate + acid -> carbon dioxide + water
CO32- (s) + 2H+ (aq) -> CO2 (g) + H2O (l)
sulfate test
- add dilute hydrochloric acid and look for effervescence
- if there is none, add barium chloride solution
- if sulfate ions are present, they will form a white precipitate with the barium ions from the barium chloride
NOTE: the hydrochloric acid is to get rid of any traces of carbonate or sulfite ions as both of these would also produce a precipitate)
sulfate test word and symbol equation
barium ions + sulfate ions -> barium sulfate
Ba2+ (aq) + SO42- (aq) -> BaSO4 (s)
halides test
- dissolve the sample in water
- add nitric acid (HNO3)
- add silver nitrate (AgNO3) solution
- if the halide ions are present, a precipitate forms with the silver ions from the silver nitrate
NOTE: its important to add the HNO3 in step 2 because silver ions also form precipitates with other anions
what colour precipitate does a chloride ion (Cl-) give?
white
what colour precipitate does a bromide ion (Br-) give?
cream
what colour precipitate does a iodide ion (I-) give?
yellow
what is the ionic formula for the formation of silver chloride?
Ag+ (aq) + Cl- (aq)-> AgCl (s)
what is the ionic formula for the formation of silver bromide?
Ag+ (aq) + Br- (aq) -> AgBr (s)
what is the ionic formula for the formation of silver iodide?
Ag+ (aq) + I- (aq) -> AgI (s)