Thermodynamics Flashcards

(43 cards)

1
Q

what system allows both energy and matter to be exachanged with the surroundings

A

open system

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2
Q

what system allows only energy to be exachanged with the surroundings

A

closed system

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3
Q

what system allows neither energy nor matter to be exachanged with the surroundings

A

isolated system

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4
Q

is glucose low entropy or high entropy and why?

A

low entropy because of the precise way of bonding

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5
Q

What is the measure of the spread of energy and matter

A

Entropy

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6
Q

what is the amount of heat in a system

A

enthalpy

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7
Q

is a process spontaneous or non spontaneous if there is an input of energy

A

non spontaneous

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8
Q

is a process spontaneous or non spontaneous if there is no input of energy

A

spontaneous

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9
Q

system takes heat from surroundings

A

endothermic

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10
Q

ΔH positive

A

endothermic

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11
Q

release of heat to surroundings

A

exothermic

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12
Q

ΔH is negative

A

exothermic

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13
Q

do spontaneous processes prefer to tend to be exothermic or endothermic

A

exothermic

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14
Q

is greater entropy spontaneous or non spontaneous

A

spontaneous

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15
Q

free energy of product < free energy of reactant

A

spontanous and ΔG is negative

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16
Q

free energy of product > free energy of reactant

A

ΔG is positive and non spontaneous

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17
Q

free energy of reactant > free energy of product

A

ΔG is negative and spontaneous

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18
Q

free energy of reactant < free energy of product

A

non spontanous and ΔG is positive

19
Q

spontanous process in terms of free energy

20
Q

what type of free energy process is when free energy of reactant > free energy of product? exergonic or endergonic

A

exergonic ΔG is negative

21
Q

what type of process is when free energy of product > free energy of reactants? exergonic or endergonic

A

endergonic ΔG

22
Q

what type of free energy process is non spontaneous

23
Q

what do you call the amount of energy to start a reaction

A

activation energy

24
Q

when can an endothermic reaction be exergonic

A

when ΔS (enthalpy) is too big such as when ice melts

25
what do you call the state when the no. of reactant molecules to product = no. of molecules being converted back to reactants?
equilibrium
26
what happened when there is equilibrium
no more overall change in concentration of products and gradients
27
why is life able to have increasing entropy?
because it is an open system
28
why do we need to constantly eat?
because entropy is constantly increasing which breaks down cellular components
29
what kind of system is earth?
closed
30
what is a metabolic pathway?
a metabolic pathway is a series of individual reactions that make up metabolism that occur one reaction at a time
31
what is a catabolic pathway
a series of chemical reactions to break doen complex molecules into smaller and less complex ones
32
what type of metabolic pathway is cellular respiration
catabolic pathway
33
what is an anabolic pathway
a pathway that converst smaller simple molecules to latger complex ones
34
how many carbons does ATP have?
5 carbons
35
how many phosphate groups does ATP have
3 phosphate groups
36
what is ATP made of?
5 carbon sugar (ribose), 3 phosphate groups, and a nitrogenous base
37
how does ATP release energy
ATP releases energy when the terminal phosphate group is broken because there is a greater energy released when ADP and Pi are formed
38
what mind of system are biological systems
open systems
39
What is the first law of thermodynamics
Energy is neither created nor destroyed
40
what is the second law of thermodynamics
the total entropy of the system is always increasing
41
when can the entropy of a system decrease
when the increase of entropy in the surroundings is greater
42
do all cellular reactions have negative free energy change?
yes
43
what is a metabolic pathway
a metabolic pathway is a linked series of chemical reactions occurring within a cell