Thermodynamics and Engines (need some editing) Flashcards
What is the first law of thermodynamics?
Q=ΔU+W
- the energy transferred to a system through heating is equal to the sum of the increase in internal energy and the work done by the system
When is Q positive?
when energy is transferred to the system by heating
when is ΔU positive?
when there is an increase in temperature
when is W positive?
when work is done by the system
What is an Open system?
-e.g?
matter can go flow in and out the system
-aerosol can
what is a closed system?
-e.g?
no matter can enter or leave the system
-air inside a balloon
what is an ideal gas?
-perfectly elastic collisions between molecules
-no intermolecular forces
-no potential energy = internal energy is equal to the sum of the kinetic energies of all its particles
what is the ideal gas equation?
pV= nRT
what is the equation between pressure, volume and temperature?
p₁V₁/T₁ = p ₂V ₂/T ₂
What is an adiabatic process?
no heat leaves or enter the system
- Q=0
- ΔU=-W
what is the equation for an adiabatic process?
pVˠ=constant
what is an isothermal process?
the temperature of the system remains constant
-ΔU=0
- Q=W
what is the equation for an isothermal change?
pV=constant
what is a constant pressure change?
(isobaric)
the pressure of the system remains constant
what is the equation for a constant pressure change?
W=pΔV
what is a constant volume change?
(Isochoric)
the volume of the system remains the same
- W=0
- Q=ΔU
what is the area beneath the pV curve?
the work done during the process
what does isothermal mean?
constant temperature
How do you find the work done per cycle on a pV graph?
the area of the loop
What are the Four steps in a four stroke petrol engine?
- Induction
- Compression
- Expansion
- Exhaust
Explain what happens during Induction?
(four stroke petrol engine cycle)
the piston moves down, gas mixture drawn in through inlet valve
-volume of gas increases
-pressure is constant
Explain what happens during Compression?
(four stroke petrol engine cycle)
inlet valve is closed and cylinder moves up, doing work on the gas
-volume of gas decreases
-pressure increases
mixture is then ignited and temperature and pressure rapidly increases at almost constant volume
Explain what happens during Expansion?
(four stroke petrol engine cycle)
gas mixture expands, doing work on the piston causing it to move down the cylinder and exhaust valve opens.
- pressure drops to slightly above atmospheric pressure
Explain what happens during Exhaust?
(four stroke petrol engine cycle)
piston moves up the cylinder, forcing the burnt gas out through the open exhaust valve