topic 3: calculations Flashcards

(12 cards)

1
Q

how do you use the mass = moles x Mr equation?

A
  1. RTQ
  2. sub the digits you know into the equation
    3.use the ratio (think of it like a fraction: divide by the start number and multiply by the end number)
  3. convert the moles into the required units
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2
Q

how do you calculate the percentage mass of an element in a compound?

A

mass of element/ mass of compound(Mr) x100

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3
Q

what’s the conversion of dm^3 to cm^3?

A

1 dm^3 = 1000cm^3 (x 1000)

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4
Q

what are the TWO equations for gases and moles

A

gas volume(cm^3) = moles x 24,000
gas volume (dm^3) = moles x 24

(if its cm^3 x 24,000 if its in dm^3 x 24)

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5
Q

name the units of concentration

A

mol/dm^3

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6
Q

what is the equation for solutions and concentrations?

A

concentration (mol/dm^3) = mol/volume (dm^3)

if the volume is in cm^3, divide it by 1000 to make it dm^3

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7
Q

what is the equation to calculate percentage yield?

A

actual yield or experimental yield = how much product you actually make (given to you in the question)
theoretical yield or maximum yield = how much can be made if it is fully reacted ( what you work out from mole calculations)

percentage yield = actual yield / theoretical yield (should always be less than 100)

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8
Q

what factors mean the actual yield doesn’t produce as much as the theoretical yield?

A

Incomplete Reactions:
Not all of the reactants may react

Side Reactions:
Other reactions can occur alongside the main reaction

Losses during Product Recovery:
During processes like filtration, transfer, washing, and drying, some of the product can be lost

Impurities in Reactants:
Reactants may not be 100% pure.

Equilibrium Limitations:
In reversible reactions, the reaction may reach equilibrium before all the reactants are converted into products, limiting the yield.

Measurement and Experimental Errors:
Errors in measuring reactants or products, and limitations of the experimental apparatus

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9
Q

what is the empirical formula?

A

Empirical formula = simplest whole-number ratio of atoms

Molecular formula = actual number of atoms in a molecule

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10
Q

how do you calculate the empirical formula?

A
  1. RTFQ
  2. use the table method
  3. separate out each element with their masses or percentages in the column below
  4. calculate the moles using mass/Mr x moles
  5. ratio the moles
  6. multiply up if needed to calculate the simplified ratio
  7. write down the empirical formula
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11
Q

how do you calculate the molecular formula from the empirical formula?

A
  1. calculate empirical formula using the tablev method
  2. work out the total Mr of the empirical formula
  3. Mr of molecular formula/mr of empirical formula
  4. multiply the empirical formula by the the number you get from the fraction

example: an organic compound has the empirical formula of CH2 and an Mr of 28. what is the molecular formula?

mass of CH2 = (12+2x1) = 14
28/14 = 2
CH2 x 2 = C2H4

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12
Q

how do you calculate water of crystallisation?

A

use the table method similar to calculating the empirical formula

  1. list all of the salts and water in the table
  2. calculate the Mr beneath them
  3. using their experimental masses, calculate there moles

3.simplify the ratio by dividing by the smallest

  1. write out your formula

note: answer should always be between 1 and 12

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