Topic 4 - Acids and bases Flashcards

1
Q

What is the pH scale an indication of?

A

the hydrogen ion concentration and runs from below 0 to above 14

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2
Q

A neutral solution has

A

equal concentrations of H+(aq) and OHˉ(aq) ions

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3
Q

Water is neutral because

A

it dissociates according to the equation
H2O(l) ⇌ H+(aq) + OH−(aq) producing equal concentrations of hydrogen and hydroxide ions.

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4
Q

At any time, only a few
water molecules are

A

dissociated into free ions

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5
Q

What does ⇌ mean?

A

that a reaction is reversible and occurs in both directions

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6
Q

Acidic solutions have

A

a higher concentration of H+(aq) ions than OHˉ(aq) and have a pH
below 7.

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7
Q

Alkaline solutions have

A

a higher concentration of OHˉ(aq) ions than H+(aq) ions and have a pH above 7.

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8
Q

Dilution of an acidic solution with water will

A

decrease the concentration of H+(aq) and the pH will increase towards 7

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9
Q

Dilution of an alkaline solution with water will

A

decrease the concentration of OHˉ(aq) and the pH will decrease towards 7

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10
Q

What do soluble non-metal oxides form when they dissolve in water

A

acidic solutions

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11
Q

What do soluble metal oxides form when they dissolve in water?

A

alkaline solutions

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12
Q

metal oxide + water

A

metal hydroxide

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13
Q

Bases

A

neutralise acids

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14
Q

What compounds are bases?

A

metal oxides, metal hydroxides, metal carbonates and ammonia

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15
Q

Bases that dissolve in water

A

form alkaline solutions

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16
Q

What is a neutralisation reaction?

A

when a base reacts with an acid to form water. A salt is also formed in this reaction.

17
Q

metal oxide + acid
(neutralisation)

A

= salt + water

18
Q

metal hydroxide + acid
(neutralisation)

A

= salt + water

19
Q

metal carbonate + water (neutralisation)

A

= salt + water + carbon diocxide

20
Q

What does the name of the salt from neutralisation depend on?

A

the acid and base used

21
Q

What do hydrochloric acid, sulfuric acid, and nitric acid produce when they react with bases?

A

Hydrochloric acid produces chlorides
Sulfuric acid produces sulfates
Nitric acid produces nitrates

22
Q

What are spectator ions?

A

ions that remain unchanged by the reaction

23
Q

How can spectator ions be identified?

A

by using reaction equations

24
Q

What is the neutralisation reaction equation (without spectator ions) for metal oxides?

A

2H⁺(aq) + O²⁻(s) → H₂O(ℓ)

25
What is the neutralisation reaction equation (without spectator ions) for metal hydroxides?
H⁺(aq) + OH⁻(aq) → H₂O(ℓ)
26
What is the neutralisation reaction equation (without spectator ions) for aqueous metal carbonates?
2H⁺(aq) + CO₃²⁻(aq) → H₂O(ℓ) + CO₂(g)
27
What is the neutralisation reaction equation (without spectator ions) for soluble metal carbonates?
2H⁺(aq) + CO₃²⁻(s) → H₂O(ℓ) + CO₂(g)
28
In an acid-base titration, what is the concentration of the acid/base determined by?
accurately measuring the volumes used in the neutralisation reaction
29
What is an indicator used for in an acid/base titration?
to show the end-point of the reaction
30
Given a balanced equation for the reaction occurring in any titration (concentration)
the concentration of one reactant can be calculated given the concentration of the other reactant and the volumes of both solutions
31
Given a balanced equation for the reaction occurring in any titration (volume)
the volume of one reactant can be calculated given the volume of the other reactant and the concentrations of both solutions
32
What can neutralisation reactions be used to prepare?
soluble salts
33
How can titration be used to produce a soluble salt?
by noting the volumes of acid and alkali, then repeating the reaction without the indicator to produce an uncontaminated salt solution. The solution can then be evaporated to dryness.
34
What happens after titration to produce a soluble salt?
the reaction is repeated without the indicator, and the resulting salt solution is evaporated to dryness.
35
What is the process for producing soluble salts from insoluble metal carbonates or oxides?
excess base is added to the acid, the mixture is filtered, and the filtrate is evaporated to dryness.