Unit 1 Flashcards

(28 cards)

1
Q

Ionisation energy

A

Energy required to pull one mole of electrons away from one mole of gaseous atoms

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2
Q

Electronegativity

A

Atom which has a strong attraction for bonding is said to be highly electronegative

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3
Q

Collision theory says that a chemical reaction takes place when

A

Molecules have sufficient energy known as the Ea

Molecules collide with the correct geometry

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4
Q

The number of collisions is affected by

A

Concentration
Particle size
Pressure

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5
Q

Activation energy is affected by

A

Temperature

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6
Q

How does increasing the temperature affect the reaction rate

A

More particles will have the minimum energy and therefore more reactions will take place

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7
Q

What is activation energy

A

Ea

Sufficient energy for a reaction to take place

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8
Q

Catalysts increase reaction rate by

A

Allowing the reaction to take place via an alternative route that has a lower activation energy

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9
Q

Two types of catalyst

A

Heterogeneous- different state from substrate

Homogeneous- same state

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10
Q

How to measure relative rate

A

RR=1/time taken for reaction

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11
Q

Enthalpy

A

Measure of chemical potential energy contained in a substance

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12
Q

Change in enthalpy =

A

Hp-Hr

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13
Q

In an exothermic reaction the products have_____ energy than the reactants

A

Less

Therefore always negative

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14
Q

In an endothermic reaction the products have_____ energy than the reactants

A

More

Therefore always positive

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15
Q

Intermolecular bonding

A

Van der waals and between different molecules eg water and water

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16
Q

Intramolecular bonding

A

Bonding within a molecule eg hydrogen and oxygen in water

17
Q

Non polar

A

Pure equal forces of attraction

18
Q

Polar

A

Slightly negative or slightly positive

19
Q

Ionic

A

Very electronegative atom takes an electron away from the other, forming an ion

20
Q

Properties of ionic

A

High melting point
Conducts electricity when molten or solution
Always solid room temp

21
Q

What to remember about solubility of substances

A

Like dissolves in like

22
Q

Covalent molecular properties

A

Any state at room temp
Lower melting point
Never conducts

23
Q

Covalent network substances

A

Carbon
Silicon
Boron

24
Q

London dispersion forces

A

Weak electrostatic attractions due to a temporary dipole forming
Can be found in everything
Only force of attraction for non polar
As number of electrons increase, strength of LDF increases

25
Dipole
Molecules in which an unequal distribution results in one side being slightly charged
26
Permanent dipole-Permanent Dipole
Electrostatic attractions between permanent dipoles in molecules Only for polar Strong
27
What substances have PDPPDP
Aldehydes and ketones
28
Hydrogen bonding
Occurs when hydrogen is bonded next to a highly electronegative element such as oxygen, nitrogen or fluorine Occurs in water very strong