Unit 3 Flashcards

(68 cards)

1
Q

Three types of Intermolecular Forces

A
  1. Dipole-Dipole
  2. H Bonds
  3. London Dispersion
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2
Q

What are dipole dipole bonds and its properties?

A

polar molecule attraction

melts and boils at low temps due to weak attraction - gases and liquids at room temps

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3
Q

What are H bonds and what are its properties?

A

When H gives up its e-, it has a + charge

High boil and melt temps due to STRONG attraction

(liquids)

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4
Q

Why are H bonds the strongest?

A

There is no electron shielding so the attraction is much much stronger

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5
Q

What are London Dispersion Forces

A

Depends on random motion of e-: higher number of e- = higher attraction =
higher melting and boiling points

(gases)

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6
Q

What is the weakest IMF?

A

London Dispersion Forces due to the randomness

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7
Q

What kind of molecule does not experience IMFs?

A

Ionic Molecules and they are SOLIDS at room temp

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8
Q

What happens to Ionic bonds when they change phases?

A

bonds are broken

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9
Q

What happens to covalent bonds when they change phases?

A

bonds are NOT broken

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10
Q

What are the melting point <> stuff

A

network covalent > ionic > metallic > covalent

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11
Q

Vapor Pressure

A

molecules are in constant motion.
If they hit hard enough, they can escape from their IMF

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12
Q

if temperature rises, vapor pressure…

A

increases

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13
Q

if there are stronger IMF, vapor pressure

A

is weaker

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14
Q

What is the rule for dissolving?

A

Like dissolves like

polar dissolves polar

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15
Q

Electrolytes

A

the ions dissolved from ionic bonds, which are great for electric conductivity

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16
Q

What does distillation do?

A

Takes advantage of different boiling points to separate mixtures of substances.

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17
Q

What does a Maxwell Boltzmann diagram tell me?

A

Demonstrates the range of velocities for the molecules of gas.

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18
Q

If temperature rises, Kinetic Energy…

A

increases

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19
Q

Effusion

A

rate of gas diffusing through microscopic holes

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20
Q

If temperature rises, rate of effusion…

A

increases

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21
Q

If mass of the individual gas is bigger, rate of effusion…

A

decreases

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22
Q

Ideal Gas Equation

A

PV = nRT

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23
Q

Combined Gas Law

A

(P1V1)/T1 = (P2V2)/T2

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24
Q

Boyle’s Law

A

P1V1 = P2V2

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25
Charles's law
V1/T1 = V2/T2
26
What does Dalton's law state?
Mixture of gases' pressure is the sum of the individual gases' pressure in the mixture
27
Calculation of Partial Pressure
(partial pressure) = (Total pressure) x (percentage of gas in total)
28
When do deviations from Ideal Behavior occur?
1. Low temperatures 2. High Pressures Volume becomes relevent and IMFs happen
29
stronger IMFs mean _________ devations
more
30
more e- mean _________ devations
more
31
Density equation
D = m/v grams / Liters
32
Density equation based on Ideal gas Law
P (MM) / RT
33
Molar Mass calculation based on Ideal Gas Law
DRT / P
34
Energy change for electromagnetic radiation equation?
E = hv h = plank's constant v = frequency in s^-1
35
What is plank's constant?
6.626 x 10^-34 Joule seconds
36
Speed of light equation
c = vλ (speed of light) = (frequency in s^-1) (wavelength in meters)
37
Speed of light?
2.998 X 10^8 ms^-1
38
Beer's law?
A = abc (absorption) = (molar absorptivity) (path length) (concentration)
39
According to Beer's Law, the higher concentration...
the higher absorption
40
1 torr= ?
1 torr = 1 mmHg 760 mmHg = 1 atm
41
Rf in paper Chromatography is...
(d of solute) / (d solvent)
42
non permanent dipole
london-disperson forces
43
what are ionic solids held together by
electrostatic attraction
44
Why are ionic solids unable to bend?
because they have a specific +/- attraction structure
45
Why are metallic solids able to bend?
because they have a random e- soup and they can bend wherever without disrupting the IMF
46
Why are covalent networks so hard to melt?
there are no free e-
47
according to Coulomb's' law, stronger charger and smaller distance means -
stronger attraction
48
amorphous structure
ranomdly arranged molecules in a solid
49
Crystalline structure
strictly arranged molecules in a solid
50
If temperature is held constant, a smaller molecule has a _______ speed than a larger molecule.
greater
51
Lower T means lower P for real gases...
P is even lower due to IMF
52
Lower V means higher P for real gases...
P is even higher due to mass being significant
53
Heterogenous
mixture of two or more unevenly mixed substances
54
Homogenous
mixture of two or more evenly mixed substances
55
In Chromatography what are the three components?
1. mobile phase 2. sample 3. stationary phase
56
Beer's Law
(Absorption) = abc a = molar absorptivity b = path length c = concentration
57
microwave waves...
rotate the molecule
58
infared waves...
vibrate the molecule
59
visible waves...
makes the molecule glow - e- goes to higher state
60
Ultraviolet waves...
breaks the bonds because the e- is so excited
61
Transmittance
the amount that comes through the light
62
Transmittance equation
(Amount Out) / (Amount In)
63
Ion Dipole
the attractive force between a charged ion and a polar molecule
64
Average KE equation
3/2 x (R/N) x T R = constant (8.314 J/mol . K) N = Avogadro's # T = temp in K
65
absorption
the light that the substance absorbs
66
emission
the light that the substance emits - what we see
67
Different concentration means...
same emission, different absorption
68
larger molecules are __________ polarizable
more easily