Unit 9 Flashcards

1
Q

what equals a high entropy

A

a more dispersment of moleucles

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2
Q

what does more molecules mean in terms of entropy

A

a higher entropy

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3
Q

State the levels of entropy in order for the state of matter

A

Solid
Liquid
Gas (most entropy)

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4
Q

What are the three degrees of freedom in molecules

A

translational, vibrational, and rotational

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5
Q

what happens when there are more degrees of freedom

A

a higher entropy

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6
Q

what is a solution and its abbreviation

A

a molecule that is mixed with water and known as aq

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7
Q

what is the variable and unit for entropy

A

S, J/K

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8
Q

what does thermodynamically favorable mean in terms of G

A

G IS LESS THAN ONE

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9
Q

define thermodynamically favored

A

the reaction just happens on it’s own with no energy required

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10
Q

When a -H and a +S are evaluated what is the sign of the G value and is it thermodynamically favored

A

The G is always negative, favored

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11
Q

When a -H and a -S are evaluated what is the G value and is it thermodynamically favored

A

The G vallue is undetermined. It depends on the temperature. It will be favored if there is a low temperature

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12
Q

When a +H and a +S are evaluated what is the G value and is it thermodynamically favored

A

The G value is undetermined. It depends on the temperature. it will be favored if there is a high temperature

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13
Q

When a +H and a -S are evaluated what is the G value and is it thermodynamically favored

A

Not every thermodynamically favored

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14
Q

What is kinetic control

A

It means that the reaction is favorable but they have extremely high activation energies.

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15
Q

answer:

when G<0 k is
when G=0 k is
when G>0 K is

A

K is >1
K=1
K <1

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16
Q

what is coupling

A

a reaction, originally unfavorable, that occurs in multiple steps to produce a thermodynamically favorable reaction

17
Q

what occurs at the anode

18
Q

what occurs at the cathode

19
Q

what is oxidixzation

A

when an electrons are lost so it’s charge goes up

20
Q

what is reduction

A

when an electron is gained so it’s charge goes down

21
Q

oxidization number rule for group 1 metsls

22
Q

oxidixation number rule for group 2 metals

23
Q

oxidixation number rule for oxygen

24
Q

oxidixation number rule for hydrogen

A

+1 except -1 with a metal

25
oxidixation number rule for flourine
-1
26
oxidixation number rule for chlorine
-1 except with O or Fwh
27
what oxidizztion number does a solid have
0
28
if an element has a higher standard reduction potential what does that mean
it is more likely to be reduced
29
if an element has a lower standard reduction potential what does that mean
it is jmore likely to be oxidized
30
if voltage is psitive what is g
negative
31
which side of a galvanic cell is the cathode
the one the gains mass, where electrons are being flowed to, where it is being reduced
32
which half reox reaction flips if you need to flip one
the more negative one
33
to find the E of a cell what do the electrons have to e , if you multiply what happens to the voltage
canceled out voltage stays the same
34
what two things causes an increase in voltage q
increase in cathode molarity decrease in anode molarity
35
what two things causes a decrease in voltage
decrease in cathode molarity increase in anode molarity
36
when you add reactions together how do you find the new k
multiply