Week 7 Flashcards

(38 cards)

1
Q

Cycloalkanes is also called

A

alicylic compounds

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2
Q

Cycloalkanes (alicylic compounds) are___________ containing C-C and C-H single bonds only

A

saturated cyclic hydrocarbons

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3
Q

What is the simplest member cycloalkane?

A

cyclopropane (C3H6)

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3
Q

Cycloalkanes are represented as_______

A

polygons

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3
Q

It is the most studied, understood and is considered the most important cycloalkane

A

cyclohexane(C6H12)

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4
Q

Classifications of cyclic compounds

A

(1) Homocyclic compounds
(2) Heterocyclic compounds

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4
Q

These are cyclic compounds having atoms of the same elements as their ring members

A

Homocyclic compounds

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4
Q

(True or False)
Cycloalkanes are represented as polygons with the understanding each corner to a C atom where requisite number of H atom is attached considering its divalent nature

A

False
(tetravalent)

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5
Q

Homocyclic compounds consist of C atoms only are known as

A

Carbocyclic compounds or carbocycles

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5
Q

These are cyclic compounds having atoms of different elements as ring members including carbon atoms

A

Heterocyclic compounds

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6
Q

(True or False)
Heterocyclic compounds are cyclic compounds having atoms of the same elements as their ring members

A

False
(different elements)

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6
Q

(True or False)
Homocyclic compounds are cyclic compounds having atoms of different elements as ring members including carbon atoms

A

False
(same elements)

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6
Q

(True or False)
Heterocyclic compounds may contain oxygen, nitrogen, sulfur or halogens in place of C atom in the ring

A

False
(not halogens)

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7
Q

We name compounds containing two fused or bridged rings as ________

A

bicycloalkanes

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8
Q

(True or False)
We interpose an expression in parenthesis within the name that denotes the number of carbon atoms in each bridge

A

False
(brackets)

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9
Q

First two members are_____ ,next three members are _____,_ and higher ones are _____

A

gases, liquids, solids

10
Q

(True or False)
Cycloalkanes are soluble in water, alcohol and ether

A

False
(insoluble in water)

11
Q

(True or False)
Cycloalkanes’ boiling points show a gradual increase with increase of molecular mass

12
Q

(True or False)
Cycloalkanes’ boiling points are lower than those of isomeric alkenes or corresponding alkanes

A

False
(higher)

13
Q

(True or False)
Cycloalkanes’ density increase gradually with increase of molecular mass

14
Q

(True or False)
Lower numbers are lighter than water and floats over it

15
Q

________with halogens in the presence of light occurs in all cycloalkanes

A

Substitution reaction

15
Q

Lower members undergo _____ with H2, X2 and HX.

A

addition reaction

16
Q

(True or False)
Substitution reaction with halogens in the presence of light occurs in all cycloalkanes

17
(True or False) Lower members undergo substitution reaction with H2, X2 and HX.
False (addition reaction)
18
(True or False) The tendency of forming addition compounds increases with increase in size of ring
False (tendency of forming addition compounds decreases)
19
It is an increase in energy when tetrahedral bond angles deviate from the optimum angle of 109.5°
Angle strain
20
Cycloalkanes are halogenated in the presence of sunlight or UV light like alkane
Free radical substitution
21
α-ω from dihalides having halogen atoms on two ends of carbon chains (α-ω dihalides) with Na or Zn dust gives rise to the formation of cycloalkanes called
Intramolecular Wurtz Reaction or Freund reaction
22
This can be used to prepare cycloalkanes from three to six carbon atoms
Intramolecular Wurtz Reaction or Freund reaction
23
In the medical application, cycloalkanes are used as an __________ in the production of drugs
organic solvent
24
(True or False) Cycloalkanes are utilized in the manufacture of hair products as well as in the food industries
True
25
The cycloalkane called ______ is used as an anesthetic agent in medical field
cyclopropane
26
(True or False) The cycloalkane called cyclohexane is used as an anesthetic agent in medical field
False (cyclopropane)
27
(True or False) Carboplatin which is derived from cyclopentane is used to treat cancer
False (cyclobutane)
28
is derived from cyclobutane is used to treat cancer
carboplatin
29
(True or False) Some of cycloalkanes are used for pigmentation purposes and also used as fragrances in perfume manufacturing sector
True
30
Some of cycloalkanes are found in the _____ of plants and animals as _________
tissues steroids