Improved Model: Orbitals - Atomic Structure (3.3) Flashcards

1
Q

Electrons are not really confined to circular orbits around the nucleus, rather _______

A

they form electron clouds/orbitals.

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2
Q

How many different types of atomic orbital are there?

A

4

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3
Q

How many s - orbitals are there per sublevel?

A

1

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4
Q

Which orbital fits around each other with the nucleus in the middle?

A

S - orbital

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5
Q

Which other names are given to p-orbitals?

A

dumbell or “figure of 8”.

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6
Q

Each p-orbital points in a different direction. True or False?

A

True

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7
Q

P- orbitals do not fit together to make the p-sublevel. True or False?

A

False - P-orbitals fit together to make the p-sublevel.

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8
Q

How many orbitals are there in each d-sublevel?

A

5

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9
Q

There are 6 f-orbitals in each f-sublevel. True or False?

A

False - there are 7 f-orbitals in each f- sublevel.

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10
Q

Why do can each orbital only hold 2 electrons?

A

This is explained through sublevels and why they exist, as they can hold different numbers of electrons.

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11
Q

Energy levels = electron shells. True or False?

A

True

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12
Q

An element in the d-block has its outer electron in the d-orbital. True or False?

A

True

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13
Q

Energy levels can be made up of multiple orbitals. True or False?

A

True

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14
Q

All orbitals in a sub-level have the same amount of energy. True or False?

A

True

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15
Q

What does the Aufbau principle state?

A

You must fill orbitals from the lowest to the highest energy.

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16
Q

What does Hund’s rules state?

A

Due to electron repulsion, you must fill orbitals singularly before pairing them up.

17
Q

What does Pauli exclusion principle state?

A

To minimise electron repulsion, you must pair electrons only if they have opposite spins (up and down positioning).

18
Q

Why does sulfur have a lower first ionisation energy than phosphorus?

A
  • Sulfur has a pair of electrons in its outer p-orbital, whereas phosphorus does not.
  • Due to this, paired electrons repel each other slightly, therfore less energy is required to remove 1 electron in sulfur.