11 Air Monitoring And Sampling Flashcards

(71 cards)

1
Q

What instrument can detect, identify, and measure all hazmat

A

Not one device can measure all

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2
Q

When can an operations level responder do air monitoring and sampling

A

With proper training, under direction of hazmat tech or allied pro, or with written sop

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3
Q

Air monitoring can be an important as peck of mitigation, assisting in the following tasks

A

ID hazards
Determine appropriate ppe, tools, equipment
Determine perimeter and scope of incident
Check effectiveness of defensive ops
Ensure efficacy of Decon
Detecting leaks
Monitor Decon runoff

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4
Q

Instrument reaction time

A

Elapsed time from air moving into device to reading provided

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5
Q

Monitoring must be done at different levels in the air because

A

Gasses vary in specific gravity, some lighter or heavier causing sinking or rising

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6
Q

Dose

A

Quantity of chem ingested or absorbed into body

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7
Q

Concentration

A

Quantity of chem inhaled, percentage of chem mixed in air or water

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8
Q

Parts per million measures concentration in what mediums

A

Water or air

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9
Q

Exposure limits may be expressed in terms such as

A

Threshold limit value TLV
short term exposure limit STEL
threshold limit values ceiling TLV-C
Permissible exposure limit PEL

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10
Q

Concentrations that are high enough to cause serious injury or death are expressed in terms of

A

IDLH immediately dangerous to life or health

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11
Q

The lower the exposure limit of a chemical…

A

The potentially more harmful it is

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12
Q

You should be safe from any toxic effects from an exposure if

A

Your exposure level never exceeds the lowest number indicated. I

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13
Q

What should be monitored for

A

O2, radiation, corrosives, flammables, oxidizers, explosives, toxics, exothermics

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14
Q

Many detection devices require what to function properly

A

Sufficient oxygen

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15
Q

It is important to document the detection finding, such as,

A

Time of reading
Level (height) the reading was taken at
Reading obtained
Instrument used

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16
Q

Issues to consider when selecting monitoring equipment

A
Mission- rescue or control
Suspected hazards involved
Portability and user friendliness 
Instrument reaction time
Sensitivity and selectivity- how well and to what degree
Calibration
Training
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17
Q

Improperly maintained or calibrated instruments are a safety hazard because

A

Readings may be inaccurate or misleading

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18
Q

Devices should be calibrated, maintained and Deconed according to

A

Manufacturers directions

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19
Q

All devices and instruments have their strengths and

A

Limitations

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20
Q

PH should always be one of the first hazards monitored unless specific hazard is known because

A

A large percentage of hazmat incidents involve corrosives and can damage detection instruments and ppe

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21
Q

PH

A

Measurement of hydrogen ions in solution indicating strength.

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22
Q

Concentration

A

Reflects amount of acid or base mixed with water. Higher percentage, higher damage. 95 percent formic acid solution is 95 acid 5 water.

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23
Q

Each who,e ph value below 7 is how many more times acidic than the next highest value

A

10 times. 4 is 19 times more than 5 and 100 times more than 6

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24
Q

For each whole number above 7 how much more basic is it

A

10 times more than the previous. 10 is 10 times more than 9, 100 more than 8

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25
Primary methods of determining ph
Ph meters and paper
26
Ph 0-3
Strong acids
27
Ph 7
Neutral, water
28
Ph 10-14
Strong base
29
Limitations of ph paper
Close proximity or contact with hazmat Can't detect concentration Difficulty reading paper if contaminated or damaged by material being read
30
Most ph paper requires to be wetted with
Distiller water
31
Before using ph meter what must be done
Calibrated and prove rinsed with distiller water before and after use
32
Most reactive of all chem compounds
Fluorine, compounds with it are called fluorides
33
Hydrogen fluoride requires what level suit protection
Level a, extremely corrosive toxic and mildly reactive.
34
Fluoride test papers
Detects fluoride ions and gaseous hydrogen fluoride | Pink red paper turns yellow white.
35
Oxygen deficient atmosphere is be,ow what percent
19.5 percent
36
Oxygen enriched atmosphere is above what percent
23.5 percent
37
Normal air contains what gasses and percentage
20.9% O2 78.1% nitrogen 1% other or trace gasses
38
Any oxygen reading below 20.9 indicates
The presence of other contaminants displacing the oxygen.
39
Contaminants will displace oxygen proportionately, a 1% drop on oxygen is equivalent to
50,000 ppm of something else in the air.
40
Oxygen sensors degrade quickly, even when
Not in use, or in contact with oxidizers and co2
41
O2 meter limitations
Corrosives cause rapid failure Strong oxidizers cause high readings, chlorine, bromine, fluorine Sensors deteriorate over time and need replacing Humidity, temp and atmospheric pressure affect monitors
42
Cgi
Combustible gas indicator | Aka lel meters
43
Cgi measures gas in three ways
Percent of lel Ppm Percent of gas by volume of air
44
Typically lel meters will alarm at what
10 percent the lel
45
Common calibration gases for cgi
Methane, pentane, propane, hexane
46
Conversion factors
Aka response curves, aka multipliers | Conversions from calibrated gas to gas being metered
47
When using cgi the atmosphere must have sufficient oxygen to render accurate reading because
A combustion chamber is used and oxygen variances will effect rare of combustion and reading.
48
Factors influencing cgi readings
``` Catalyst poisons Concentrations exceeding 100% lel Concentrations exceeding uel Chlorinated hydrocarbons Oxyacetylene mixtures ```
49
Limitations of cgi
Sensitive to battery life, loses responsiveness with power Corrosive gas damage sensors Meter response slow in cold weather Cell phones, high voltage, other emf, interfere with readings Oxygen sensitivity,
50
Toxicity is also a factor of exposure over
Time
51
Median lethal dose
Ld50
52
Lethal concentration
Minimum concentration of inhaled substance to cause death, 1-4 hrs
53
Typical four gas meter will detect
Lel, oxygen, co, hydrogen sulfide
54
Photoionization detectors
PIDs use uv lamp to ionize samples of gas to detect low concentrations of organic or inorganic vapors, can't determine specific substance but indicate a contaminant is present.
55
Colorimetric tubes
Reagent in tube changes color when exposed to specific chemical or family.
56
Problems with colorimetric tubes
Determine presence of material but not unidentified products. Error rate of 25-35%
57
Curie | Ci
English system for radioactivity measurement. Indicating number of radioactive decays or disintegrations in a time Large amount
58
Becquerels Bq
International radioactivity measurement, small amount
59
Amount of radiation exposure is expressed in
Rem (large amount of radiation) or Millirem
60
Roentgen | R
Measuring radiation exposure only for gamma and X-ray on US DOSIMETERS r/hr
61
Radiation absorbed dose | RAD
Used to measure the amount of radiation absorbed by a material
62
Roentgen equivalent in man | REM
Absorbed dose equivalent in human body. All types of radiation. Takes energy absorbed in RAD and bio effect on body based on different types of radiation. Used to set dose limits.
63
Simplest and most affordable tool available for responders to detect radiation and contamination
Hand held portable survey instruments.
64
Three groups for radiological instruments
Measuring radiation exposure Detect contamination Dose monitoring and personal dosimetry
65
Contamination can emit what types of radiation
Alpha, beta, gamma, combination
66
Two types of radiation detectors
Gas filled | Scintillation
67
Gas filled radiation detector
Radiation ionizes gas in chamber, instrument measures number of ions made.
68
Common gas filled radiation detectors
Ion chambers | Geiger- mueller GM
69
Scintillation radiation detector
Radiation interacts with crystal, usually sodium iodide, cesium iodide, or zinc sulfide. Produce small flash of light. Electronics amplify flash to create signal. Detect small amounts of radiation
70
Dosimeters are useful for tracking accumulated radiation dose Works like an odometer because
Measures total dose received over time
71
Dosimeters should be read how often
Before entering 15-20 min intervals inside hot zone Upon leaving