acids and bases Flashcards

1
Q

acid definition

A

proton donor

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2
Q

base defintion

A

proton acceptor

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3
Q

strong acid definition

A

an acid that fully dissociates

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4
Q

weak acid defintion

A

an acid that partially dissociates

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5
Q

pH=

A

-log10[H+]

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6
Q

[H+]=

A

10^-pH

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7
Q

ionic product of water (kw)=

A

[H+][OH-]

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8
Q

when calculating pH of strong acid use

A

pH=-log10[H+]

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9
Q

when calcualting pH of strong base use

A

rearrange kw=[H+][OH-] to get [H+] then use pH=-log10[H+]

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10
Q

when calcuating pH of a weak acid use

A

ka=[H+]^2/[HA] and rearrange to get [H+] and then use pH=

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11
Q

when calcuating pH of buffer use

A

ka=[H+][A-]/[HA] and rearrange to get [H+] and then use pH=

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12
Q

what does acid-base equillibria involve

A

transfer of protons

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13
Q

water is

A

slighty dissociated

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14
Q

what varies the value of Kw

A

temp
water dissociation equation endothermic

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15
Q

pKa=

A

-log10Ka
mirrors pH scale lower the pH lower the pKa value

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16
Q

in a monoprtic acid [H+] =

A

[HA]

17
Q

relationship between [HA] and [H+] in diprotic acid

A

[HA] x2 = [H+]

18
Q

in a triprotic acid [H+] =

A

[HA]/3

19
Q

what does a buffer solution do

A

maintains an approximately constant pH despite dilution or addition of small amounts of acid or base

20
Q

acidic buffer solutions contain

A

excess weak acid and the salt of that weak acid

21
Q

basuc buffer solutions contain

A

excess weak base and the salt of that weak base

22
Q

at half nuetralisation point ka=

A

[H+]

23
Q

at half netralisation piont pKa=

A

pH

24
Q

if acid is added to buffer solution

A

add to the acid

25
Q

if base is added to alkali solution

A

take from the acid