1.4 Energetics Flashcards

1
Q

Exothermic definition

A

Energy is released from the chemical to the surroundings

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Endothermic definition

A

Energy is taken in from the surroundings

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Enthalpy change definition

A

The change in heat energy at constant pressure

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What is the enthalpy change for exothermic processes?

A

Negative

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

What is the enthalpy change for endothermic processes?

A

Positive

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

What are the standard conditions?

A

100kPa
25C (298K)
1.0 mol dm-3 concentration

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

What happens to the bonds in a reaction?

A

The bonds in the reactants are broken
The bonds in the products are formed

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

What type of reaction is breaking bonds?

A

Endothermic as energy is required

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

What type of reaction is forming bonds?

A

Exothermic as it releases energy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Activation energy definition

A

The minimum energy needed to start a reaction

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Mean bond enthalpy definition

A

The energy required to break one mole of covalent bond into gaseous atoms averaged over a range of different compounds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

What type pf process is a mean bond enthalpy reaction?

A

Endothermic (positive)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Standard enthalpy of combustion definition

A

Enthaply change when one mole of substance is completely burnt in excess oxygen under standard conditions, all reactants and products in their standard states

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

What substances have a zero enthalpy of combustion?

A

Water and carbon dioxides

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Why may the enthalpy of combustion be difficult to measure?

A

Incomplete combustion may occur

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Why may some enthalpy be difficult to measure?

A

Reaction may have a very high activation energy
Reaction may be too slow
Possibility of competing reactions

17
Q

Hess’ Law definition

A

States that the enthalpy change for a chemical reaction is the same whatever the route is taken from reactants to products

18
Q

What are the types hess’ cycles

A

Bond enthalpy, formation and combustion