Redox i Flashcards

1
Q

Oxidation number

A

Tells us the loss and gain of electrons for atoms

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2
Q

Oxidation number of un combined elements or combined to identical elements

A

= 0

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3
Q

Oxidation of monatomic ions

A

The same as its charge

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4
Q

Oxidation number of atoms within molecular ions

A

The numbers add up to the charge of an ion
So use oxidation number rules of other elements eg oxygen to work it out

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5
Q

Oxidation number of neutral compounds (salt, simple covalent molecules ’)

A

The overall oxidation number is 0 so atoms within it’s oxidation number add to 0

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6
Q

Hydrogen oxidation number

A

Always +1
except metal hydrides where it’s -1
(And H2 where it’s 0)

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7
Q

Oxygen oxidation number

A

Always -2
Except in peroxides where it’s -1
And in O2 where it’s 0

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8
Q

What can also show oxidation number of a compound or ions

A

The Roman numeral

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9
Q

Sulfate/nítrate ions oxidation number

A

The Roman numeral eg sulfate (VI) shows that the oxidation number of the non oxygen element (sulfur) is +6

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10
Q

Using oxidation numbers to find chemical formulae

A

Use The Roman numerals and rules for certain elements
Assume charge is 0nu less said otherwise
Assume nitrate is NO3-, sulfate us SO4 2- etc unless told otherwise

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11
Q

Redox reaction

A

When electrons are transferred where one element is reduced and another is oxidised

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12
Q

Oxidation

A

Loss of electrons

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13
Q

Reduction

A

Gain of electrons

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14
Q

Oxidising agent

A

Makes another element lose electrons by gaining them so is reduced

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15
Q

Reducing agent

A

Loses electrons so another element can gain them and be reduced so is oxidised

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16
Q

What happens when metals form compounds?

A

Usually lose electrons and are oxidised

17
Q

What happens when non metals form compounds?

A

Usually gain electrons and are reduced

18
Q

Disproportionate reaction

A

When an element is both reduced and oxidised in a single reaction

19
Q

Half equations

A

Show the oxidation and reduction (so loss or gain of electrons respectively) of a single element in a reaction

20
Q

Half equation for an oxidation reaction

A

The electron is on the product side to show how electrons were lost from original element
And the charge as a result on products will INCREASE

21
Q

Half equation for a reduction reaction

A

The electron is on the reactant side to show how element will gain this and be reduced
And the charge on products will DECREASE

22
Q

What do 2 half equations from the same reaction form when combined?

A

The full redox reaction
But ensure the number of electrons is balanced

23
Q

How can you balance half equations?

A

First ensure all other atoms are balanced
Balance number of oxygen with H2O on side that is unbalanced
Then balance the H with H+ atoms
Then ensure overall charge is balanced on either side

24
Q

What to remember about balancing half equations?

A

The number of H also needs to be balanced so ensure only one side has H+ ions