Group 7 Flashcards

1
Q

Group 7 elements

A

Fluorine
Chlorine
Bromine
Iodine

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2
Q

What state is fluorine at room temperature?

A

Gas

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3
Q

What colour is fluorine gas?

A

Pale yellow

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4
Q

Does fluorine dissolve in water?

A

No

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5
Q

Does fluorine dissolve in organic solvents eg hexane?

A

No

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6
Q

What state is chlorine at room temperature?

A

Gas

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7
Q

What colour is chlorine gas?

A

Green

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8
Q

Does chlorine dissolve in water?

A

Yes

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9
Q

What colour is chlorine dissolved in water?

A

Pale green to colourless

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10
Q

What colour is chlorine dissolved in hexane?

A

Virtually colourless

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11
Q

What state is bromine in at room temperature?

A

Liquid

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12
Q

Bromine liquid colour

A

Red-brown

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13
Q

Does bromine dissolve in water?

A

Yes

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14
Q

Bromine water colour

A

Yellow-orange

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15
Q

Does bromine dissolve in hexane?

A

Yes

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16
Q

Bromine dissolved in hexane colour

A

Orange-red

17
Q

What state is iodine in at room temperature?

A

Solid

18
Q

Iodine solid colour

A

Grey

19
Q

Does iodine dissolve in water

A

Barely

20
Q

What colour does iodine dissolved in water form?

A

A brown solution

21
Q

Can iodine dissolve in iodine compound solvents (such as KI)?

A

Yes and forms a brown solution

22
Q

What colour does iodine dissolved in ethanol form?

A

Yellow

23
Q

What colour does iodine dissolved in hexane form?

A

Purple

24
Q

Iodine gas colour

A

Purple

25
Q

How does the reactivity of halogens change down the group?

A

Decreases

26
Q

Why does the reactivity of halogens decrease down the group?

A

Because they react by gaining an electron to complete outer shell
Going down the group, the atomic radii increases so:
Outer electrons experience more shielding due to more internal electrons
Outer shell electrons are further from nucleus
So decreased electrostatic attraction between nucleus and reacting electron due to experiencing less nuclear force
(Overcomes increase in number of protons)

27
Q

How does electro negativity of halogens change down the group?

A

Decreases down the group

28
Q

Why does electronegativity of halogens decrease down the group?

A

Because electronegativity is ability to attract bonding pair of electrons to nucleus
Going down the group the atomic radii increases so the number of electrons shielding bonded pair of electrons from nuclear charge increases and bonding pair of electrons is at a further distance from nucleus
This decreases nuclear force thus EN decreases down the group
(Overcomes increasing proton number)

29
Q

How does melting and boiling point change down the group?

A

Increases down the group

30
Q

Why does the mp/bp increase down the group?

A

Because going down group 7, there is an increase in atomic radii thus more electrons per atom
So an increase in number of London forces formed between diatomic molecules
Therefore, more energy is needed to overcome these London forces to melt or boil

31
Q

Why do halogens not react as easily with water?

A

Because water is a polar solvent that can form London forces, permanent dipole dipole forces AND hydrogen bonds
Halogen molecules are non polar thus do not dissolve as readily

32
Q

Why do halogens dissolve easily with organic solvents eg hexane?

A

Because they are both non polar