Bonds Flashcards

1
Q

Bond dissociation energy

A

Energy needed to break a bond homolytically

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2
Q

Homolytic bond cleavage

A

One electron of cleavage goes to each fragment of molecule and two radicals are formed

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3
Q

Heterolytic bond cleavage

A

Both electrons making up bond end up on same atom

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4
Q

What type of bond has higher dissociation energy?

A

Triple bond

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5
Q

If a molecule has a high percentage of p character is the bond strong or weak?

A

Weak and bond is longer

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6
Q

If a molecule is sp3 what is the bond angle and orbital geometry?

A

109.5 and tetrahedral

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7
Q

If molecule is sp2 what is bond angle and orbital geometry?

A

120 and trigonal planar

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8
Q

If molecule is sp what is bond angle and orbital geometry?

A

180 and linear

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9
Q

If there is one electron pair what is shape and orbital geometry?

A

Trigonal planar and bent

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10
Q

If there is one lone pair and molecule is tetrahedral what is its shape?

A

Trigonal pyramid

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11
Q

If there is two lone pairs and molecule is tetrahedral what is the shape?

A

Bent

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12
Q

Sigma bonds

A

Two electrons localized between two nuclei

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13
Q

Pi bonds

A

Double bonds

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14
Q

Vapor pressure

A

Pressure exerted by gas phase of liquid that evaporated from exposed surface of liquid.

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15
Q

If intermolecular forces are weak, what is vapor pressure?

A

High

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16
Q

What makes metals good conductors of electricity and heat?

A

Free roaming electrons

17
Q

Are molecular solids held together by intermolecular or intramolecular interactions?

A

Intermolecular