Topic 8 Flashcards
Enthalpy change define it
Enthalpy change is the energy change in a reaction at constant pressure
The measurements were made under standard conditions and the elements were in their standard states
Standard conditions
100 kPa or 1ATM pressure
298k
Exothermic reaction
Gives out heat energy
Temperature goes up
Negative enthalpy change
Endothermic reactions
Takes in heat energy
Temperature falls
Positive enthalpy change
Standard enthalpy change of reaction
Enthalpy change when the reaction occurs in the molar quantities shown in the chemical equation under standard conditions
Change of formation
Enthalpy change when one mole of a compound is formed from its elements in their standard states under standard conditions
Change of combustion
Enthalpy change when one mole of a substance is completely burned in oxygen under standard conditions
Change of neutralisation
Enthalpy change when an acid and alkali react together under standard conditions to form one mole of water
Formula for energy change
Q equals MC Delta T
Hesses law
The total enthalpy change of reaction is always the same no matter which route is taken
Breaking bonds requires
Energy
So bond breaking is endothermic
Forming bonds
Releases energy
So bond forming is exothermic
Bond energy
The amount of energy required to break one mole of the type of bond in a molecule in the gas phase