CbD - Fats and oils Flashcards

1
Q

What type of molecule are fatty acids?

A

Carboxylic acids.

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2
Q

What does saturated mean?

A

Single bonds only

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3
Q

What does unsaturated mean?

A

Contains 1 or more double bonds.

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4
Q

Structure of fatty acids

A

Long hydrocarbon tail with a carboxylic acid group at the end.

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5
Q

What can you use to distinguish between saturated and unsaturated fatty acids?

A

Bromine water

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6
Q

How can bromine water be used to distinguish between saturated and unsaturated fatty acids?

A

Double bonds (unsaturated) - the solution will decolourise (orange to colourless).

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7
Q

What are triglycerides?

A

Triesters of glycerol and fatty acids.

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8
Q

How are triglycerides made?

A

By reacting glycerol (propane-1,2,3-triol) with fatty acids.

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9
Q

What is the systematic name for glycerol?

A

Propane-1,2,3-triol

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10
Q

Through what reaction are triglycerides made?

A

Condensation (the three -OH groups on the glycerol molecules link up to the fatty acids - water is eliminated).

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11
Q

What state are fats and oils at room temperature?

A
Fats = Solid
Oils = Liquid
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12
Q

Another name for triglyceride?

A

Triester

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13
Q

What are carboxylic acid residues (properties)?

A
  • Usually unbranched hydrocarbon chains.
  • Usually an even no. of carbon atoms (up to 24, often 16 or 18.
  • Can be saturated or unsaturated.
  • Often not the same on each of the 3 ester links.
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14
Q

What do the properties of fats and oils depend on?

A

Carbon chains of the carboxylic acid residues.

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15
Q

What make carboxylic acid residues hydrophobic?

A

Long non-polar hydrocarbon chains stop the substance mixing with water.

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16
Q

What affects the melting point of oils (and fats)?

A

Lower melting point of oils related to higher degree of unsaturation.

17
Q

Why do oils have a low melting point?

A

More double bonds (unsaturated) so Id-Id bonds weaker as chains can’t get as close together.

18
Q

How do you hydrolyse the ester?

A

Heat the ester with c.NaOH to make alcohol and sodium salt.

19
Q

What is a ‘residue’?

A

Something that has reacted.